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Synthesis and Characterization of the Complexes of Pentane-24-dione with Nickel(II) and Cobalt(III): Ni(acac)2·0.5CH3OH and Co(acac)2NO3·2H2O (acac = Pentane-24-dione)

机译：戊烷-24-二酮与镍（II）和钴（III）：Ni（acac）2·0.5CH3OH和Co（acac）2NO3·2H2O（acac = Pentane- 24-二酮）

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摘要

Two mononuclear complexes, [Ni(acac)2]·0.5CH3OH (>1) and [Co(acac)2NO3]·2H2O (>2) (acac = pentane-2,4-dione), have been synthesized and characterized by single crystal X-ray analysis. Complex >1 crystallizes in the monoclinic space group P21/c with a = 9.295(4), b = 11.450(5), c = 12.974(6) Å, V = 1379.1(11) Å³, β = 92.854(7), and Z = 4. Complex >2 crystallizes in the triclinic space group P(-1) with a = 8.153(9), b = 9.925(11), c = 10.355(12), V = 746.3(15) Å³, α = 70.530(16), β = 71.154(15), γ = 80.698(16) and Z = 2. Complex >1 has a one-dimensional chain-like structure, which is extended by weak hydrogen contacts, while complex >2 shows a three–dimensional network structure.

机译：两种单核络合物[Ni（acac）2]·0.5CH3OH（> 1 ）和[Co（acac）2NO3]·2H2O（> 2 ）（acac =戊烷-2 ，4-二酮），已经合成并通过单晶X射线分析表征。络合物> 1 在单斜空间群P21 / c中结晶，其中a = 9.295（4），b = 11.450（5），c = 12.974（6）Å，V = 1379.1（11）Å > 3 ，β= 92.854（7），Z =4。复合物> 2 在三斜空间群P（-1）中结晶，其中a = 8.153（9），b = 9.925 （11），c = 10.355（12），V = 746.3（15）Å^{3 ，α= 70.530（16），β= 71.154（15），γ= 80.698（16）和Z = 2.复杂的> 1 具有一维链状结构，通过弱氢接触而延伸，而复杂的> 2 具有三维网络结构。}

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期刊名称 Molecules
作者
Yang Qu; Hai-Liang Zhu; Zhong-Lu You; Min-Yu Tan;
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作者单位

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年(卷),期 2004(9),11
年度 2004
页码 949–956
总页数 8
原文格式 PDF
正文语种
中图分类分子生物学;
关键词
Pentane-24-dione; crystal structure; cobalt(III) complex; nickel(II) complex;

机译：戊烷-24-二酮;晶体结构钴（III）络合物;镍（II）络合物;

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专利

1. Synthesis and Characterization of the Complexes of Pentane-2,4-dione with Nickel(II) and Cobalt(III): [Ni(acac)2]·0.5CH3OH and [Co(acac)2NO3]·2H2O (acac = Pentane-2,4-dione) [J] . Molecules . 2004,第11期

机译：戊烷-2,4-二酮与镍（II）和钴（III）：[Ni（acac）2]·0.5CH3OH和[Co（acac）2NO3]·2H2O（acac = Pentane- 2,4-二酮）
2. Synthesis, magnetic properties, and electronic spectra of bis(beta-diketonato)chromium(III) and nickel(II) complexes with a chelated imino nitroxide radical: X-ray structures of [Cr(acaMe)(2)(IM2py)]PF6 and [Ni(acac)(2)(IM2py)] [J] . Tsukahara Y., Kamatani T., Iino A., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2002,第17期

机译：具有螯合亚氨基亚硝基氮自由基的双（β-二酮基）铬（III）和镍（II）配合物的合成，磁性和电子光谱：[Cr（acaMe）（2）（IM2py）] PF6的X射线结构和[Ni（acac）（2）（IM2py）]
3. Polynuclear nickel(II) complexes: Preparation, characterization, magnetic properties, and quantum-chemical study of [Ni-5(OH)(Rbta)(5)(acac)(4)(H2O)(4)] (RbtaH = benzotriazole and 5,6-dimethylbenzotriazole) [J] . Tangoulis V., Terzis A., Bakalbassis EG., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1998,第13期

机译：多核镍（II）配合物：[Ni-5（OH）（Rbta）（5）（acac）（4）（H2O）（4）]的制备，表征，磁性和量子化学研究（RbtaH =苯并三唑和5,6-二甲基苯并三唑）
4. Electrochemistry Studies of UO_2(acac)_2L(acac = acetylacetonate, L = dimethyl sulfoxide, N,N-dimethylformamide, tetrahydrofuran) Complexes in Non-aqueous Solvents [C] . Seong-Yun Kim, Gunzo Uchiyama, Koichiro Mizuoka, International Symposium NUCEF . 2002

机译：UO_2（ACAC）_2L（ACAC =乙酰丙酮，L =二甲基亚甲醚，N，N-二甲基甲酰胺，四氢呋喃）复合物在非水溶剂中的电化学研究
5. Synthesis of gold complexes from diphosphine ligands and screening reactions of heterocyclic acetylacetonato (ACAC) ligands with transitional metal complexes. [D] . Nyamwihura, Rogers. 2015

机译：由二膦配体合成金配合物，以及杂环乙酰丙酮基（ACAC）配体与过渡金属配合物的筛选反应。
6. Graphene related magnetic materials: micromechanical exfoliation of 2D layered magnets based on bimetallic anilate complexes with inserted FeIII(acac2-trien)+ and FeIII(sal2-trien)+ molecules [O] . Alexandre Abhervé, Samuel Mañas-Valero, Miguel Clemente-León, 2015

机译：石墨烯相关的磁性材料：基于双金属苯甲酸酯配合物的FeIII（acac2-trien） +和FeIII（sal2-trien） +分子的二维层状磁体的微机械剥离
7. Synthesis and Characterization of the Complexes of Pentane-2,4-dione with Nickel(II) and Cobalt(III): [Ni(acac)2]Ã‚Â·0.5CH3OH and [Co(acac)2NO3]Ã‚Â·2H2O (acac = Pentane-2,4-dione) [O] . Min-Yu Tan, Zhong-Lu You, Hai-Liang Zhu, 2004

机译：戊烷-2,4-二酮与镍（II）和钴（III）配合物的合成与表征：[Ni（acac）2]×0.5CH3OH和[Co（acac）2NO3]Ã，· 2H2O（acac =戊烷-2,4-二酮）
8. Chemistry of the Metal Carbonyls. Part 78. Synthesis and X-Ray Crystal Structures of (NiOs3(mu-H)2(mu-CO)2(CO)8(PPh3)2) and (Os3Rh-(mu-H)2(acac)(CO)10) (acac = Acetylacetonate) [R] . Farrugia, L. J., Howard, J. A. K., Mitrprachachon, P., 1980

机译：金属羰基化学。部分78.（NiOs3（mu-H）2（mu-CO）2（CO）8（pph3）2）和（Os3Rh-（mu-H）2（acac）（CO）的合成和X射线晶体结构10）（acac =乙酰丙酮酸盐）

Synthesis and Characterization of the Complexes of Pentane-24-dione with Nickel(II) and Cobalt(III): Ni(acac)2·0.5CH3OH and Co(acac)2NO3·2H2O (acac = Pentane-24-dione)

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