Crystal structures of Mn(bdc)(Hspar)2(H2O)0.25·2H2O containing MnO6+1 capped trigonal prisms and Cu(Hspar)2(bdc)·2H2O containing CuO4 squares (Hspar = sparfloxacin and bdc = benzene-14-dicarboxylate)

机译：含有Mn（bdc）（Hspar）2（H2O）0.25·2H2O的晶体结构其中含有MnO6 + 1封顶的三棱柱和Cu（Hspar）2（bdc）·2H2O含有CuO4正方形（Hspar =司巴沙星和bdc =苯） -14-二羧酸盐）

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The syntheses and crystal structures of 0.25-aqua(benzene-1,4-dicarboxylato-κ² O,O′)bis(sparfloxacin-κ² O,O′)manganese(II) dihydrate, [Mn(C8H4O4)(C19H22F2N4O3)2(H2O)0.25]·2H2O or [Mn(bdc)(Hspar)2(H2O)0.25]·2H2O, (I), and bis(sparfloxacin-κ² O,O′)copper(II) benzene-1,4-dicarboxylate dihydrate, [Cu(C₁₉H₂₂F₂N₄O₃)₂](C₈H₄O₄)·2H₂O or [Cu(Hspar)₂](bdc)·2H₂O, (II), are reported (Hspar = sparfloxacin and bdc = benzene-1,4-dicarboxylate). The Mn²⁺ ion in (I) is coordinated by two O,O′-bidentate Hspar neutral molecules (which exist as zwitterions) and an O,O′-bidentate bdc dianion to generate a distorted MnO₆ trigonal prism. A very long bond [2.580 (12) Å] from the Mn²⁺ ion to a 0.25-occupied water molecule projects through a square face of the prism. In (II), the Cu²⁺ ion lies on a crystallographic inversion centre and a CuO₄ square-planar geometry arises from its coordination by two O,O′-bidentate Hspar molecules. The bdc dianion acts as a counter-ion to the cationic complex and does not bond to the metal ion. The Hspar ligands in both (I) and (II) feature intramolecular N—H⋯O hydrogen bonds, which close S(6) rings. In the crystals of both (I) and (II), the components are linked by N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds, generating three-dimensional networks.

机译：0.25-水（苯-1,4-二羧酸基-κ^{2 O，O'）双（司巴沙星-κ^{2 O，O'）的合成和晶体结构二水锰（II），[Mn（C8H4O4）（C19H22F2N4O3）2（H2O）0.25]·2H2O或[Mn（bdc）（Hspar）2（H2O）0.25]·2H2O，（I）和双（斯巴沙星-κ） ^{2 O，O'）铜（II）苯-1,4-二羧酸二水合物，[Cu（C _{19 H _{22 F _{2 N _{4 O _{3 ）_{2 ]（C _{8 H _{4 < / sub> O _{4 ）·2H _{2 O或[Cu（Hspar）_{2 ]（bdc）·2H _{2 O，（II）（Hspar =司帕沙星，bdc =苯-1,4-二羧酸酯）。（I）中的Mn ^{2 + 离子由两个O，O'形的Hspar中性分子（以两性离子形式存在）和一个O，O'形的bdc二价阴离子配位以生成扭曲的MnO _{6 三角棱镜。从Mn ^{2 + 离子到0.25占据的水分子的很长的键[2.580（12）Å]穿过棱镜的方形表面伸出。在（II）中，Cu ^{2 + 离子位于晶体反转中心，CuO _{4 方平面的几何形状是由两个O，O'-双齿的配位产生的Hspar分子。 bdc二价阴离子充当阳离子络合物的抗衡离子，并且不与金属离子键合。（I）和（II）中的Hspar配体均具有分子内N-H = O氢键，该键闭合S（6）环。在（I）和（II）的晶体中，组分通过NH-O，OH-O和CHH-O氢键连接，产生三维网络。}}}}}}}}}}}}}}}}}}}}

著录项

期刊名称 Acta Crystallographica Section E: Crystallographic Communications
作者
Zhe An; Jing Gao; William T. A. Harrison;
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作者单位

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年(卷),期 2016(72),Pt 1
年度 2016
页码 96–101
总页数 26
原文格式 PDF
正文语种
中图分类生化遗传学;生化药理学;
关键词
crystal structure sparfloxacin trigonal prismatic geometry manganese copper molecular salt;

机译：晶体结构;司帕沙星;三角棱柱形;锰;铜;分子盐;

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外文文献

1. Crystal structures of [Mn(bdc)(Hspar)2(H2O)0.25]·2H2O containing MnO6+1 capped trigonal prisms and [Cu(Hspar)2](bdc)·2H2O containing CuO4 squares (Hspar = sparfloxacin and bdc = benzene-1,4-di-carboxyl-ate) [J] . An Z., Gao J., Harrison W.T.A. Acta Crystallographica Section E: Crystallographic Communications . 2016,第1期

机译：含[Mn（bdc）（Hspar）2（H2O）0.25]·2H2O的晶体结构，含MnO6 + 1盖了三棱柱，而[Cu（Hspar）2]（bdc）·2H2O含CuO4正方形（Hspar =司巴沙星，bdc =苯） -1,4-二羧酸酯）
2. Crystal structures of [Mn(bdc)(Hspar)2(H2O)0.25]·2H2O containing MnO6+1 capped trigonal prisms and [Cu(Hspar)2](bdc)·2H2O containing CuO4 squares (Hspar = sparfloxacin and bdc = benzene-1,4-di-carboxyl-ate) [J] . An Z., Gao J., Harrison W.T.A. Acta Crystallographica Section E: Crystallographic Communications . 2016,第1期

机译：含[Mn（bdc）（Hspar）2（H2O）0.25]·2H2O的晶体结构，含MnO6 + 1盖了三棱柱，而[Cu（Hspar）2]（bdc）·2H2O含CuO4正方形（Hspar =司巴沙星，bdc =苯） -1,4-二羧酸酯）
3. Synthesis, Crystal Structures, and Properties of [Ca(H2O)2(Dmf@CB[6])(Bdc)] · DMF · 4H2O and [Ca(H2O)3(Dmf@CB[6])]Cl2 · 2H2O [J] . E. A. Kovalenko, M. Yu. Palatkina, D. G. Samsonenko Russian Journal of Coordination Chemistry . 2012,第6期

机译：[Ca（H2O）2（Dmf @ CB [6]）（Bdc）]·DMF·4H2O和[Ca（H2O）3（Dmf @ CB [6]）] Cl2·2H2O的合成，晶体结构和性质
4. Synthesis and Crystal Structure of Quaternary Copper(Ⅱ) Complex with FluoroquinoloneLigand, Cu(cip)(bpy)Cl· 2H2O [C] . International symposium on solid state chemistry in China amp; 8th Chinese national conference on solid state chemistry and inorganic synthesis : Book of abstracts . 2002

机译：含氟喹诺酮配体Cu（cip）（bpy）Cl·2H2O的季铜（Ⅱ）配合物的合成和晶体结构
5. Crystal structures of two decavanadates(V) with pentaaquamanganese(II) pendant groups: (NMe4)2V10O28{Mn(H2O)5}2·5H2O and NH3C(CH2OH)32V10O28{Mn(H2O)5}2·2H2O [O] . Maurício P. Franco, André Luis Rüdiger, Jaísa F. Soares, 2015

机译：具有五甲基锰（II）侧基的两个十钒酸盐（V）的晶体结构：（NMe4）2 V10O28 {Mn（H2O）5} 2·5H2O和NH3C（CH2OH）3 2 V10O28 {Mn（H2O）5 } 2·2H2O
6. Crystal structures of [Mn(bdc)(Hspar)2(H2O)0.25]·2H2O containing MnO6+1 capped trigonal prisms and [Cu(Hspar)2](bdc)·2H2O containing CuO4 squares (Hspar = sparfloxacin and bdc = benzene-1,4-dicarboxylate) [O] . Zhe An, Jing Gao, William T. A. Harrison 2016

机译：含有mnO6 + 1封端三角棱柱的[mn（bdc）（Hspar）2（H2O）0.25]·2H2O和含有CuO4晶格的[Cu（Hspar）2]（bdc）·2H2O（Hspar =司帕沙星和bdc =苯）的晶体结构-1,4-二甲酸酯）

Crystal structures of Mn(bdc)(Hspar)2(H2O)0.25·2H2O containing MnO6+1 capped trigonal prisms and Cu(Hspar)2(bdc)·2H2O containing CuO4 squares (Hspar = sparfloxacin and bdc = benzene-14-di­carboxyl­ate)

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Crystal structures of Mn(bdc)(Hspar)2(H2O)0.25·2H2O containing MnO6+1 capped trigonal prisms and Cu(Hspar)2(bdc)·2H2O containing CuO4 squares (Hspar = sparfloxacin and bdc = benzene-14-dicarboxylate)