Supramolecular Chemistry And Self-assembly Special Feature: New supramolecular trigonal prisms fromzinc(II)– 14710-tetraazacyclododecane (cyclen) complexes andtrithiocyanurate in aqueous solution

机译：超分子化学和自组装特征：新型超分子三角棱镜来自锌（II）– 14710-四氮杂十二烷（环）络合物和水溶液中的三硫氰尿酸酯

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The multiple bonding between multinuclear zinc(II)–1,4,7,10-tetraazacyclododecane (cyclen, a 12-membered tetraamine) complexes and multidentate ligands is an effective method for constructing supramolecular complexes having well defined and distinct structures in aqueous solution. Herein we present examples of supramolecular D3h prisms formed by self-assembly of linearly dimeric or trimeric zinc(II)–cyclen complexes with a potentially trianionic C3 subunit trithiocyanuric acid (TCA³⁻), wherein Zn²⁺—S⁻ or Zn²⁺—N⁻ coordination bonds and hydrogen bonds are responsible for stability of the multicomponent architectures in aqueous solution at neutral pH.

机译：多核锌（II）–1,4,7,10-四氮杂十二烷（周期数，12元四胺）配合物与多齿配体之间的多重键合是一种有效的方法，可在水溶液中构建结构明确且独特的超分子配合物。在这里，我们介绍由超分子D3h棱柱的例子，这些棱柱是通过自组装线性二聚或三聚的锌（II）-周期素与潜在的三阴离子C3亚基三硫氰尿酸（TCA ^{3-）形成的，其中Zn ^{2 + -S ^{-或Zn ^{2 + -N ^{-配位键和氢键负责多组分的稳定性水溶液在中性pH下的结构。}}}}}

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期刊名称 Proceedings of the National Academy of Sciences of the United States of America
作者
Shin Aoki; Mohd Zulkefeli; Motoo Shiro; Eiichi Kimura;
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年(卷),期 2002(99),8
年度 2002
页码 4894–4899
总页数 6
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入库时间 2022-08-17 12:42:54

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1. Design and Synthesis of a Stable Supramolecular Trigonal Prism Formed by the Self-Assembly of a Linear Tetrakis(Zn2+-cyclen) Complex and Trianionic Trithiocyanuric Acid in Aqueous Solution and Its Complexation with DNA (Cyclen=1,4,7,10-Tetraazacyclododecane) [J] . Zulkefeli M, Sogon T, Takeda K, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2009,第19期

机译：线性四（Zn2 + -cycln）配合物与三阴离子三硫氰尿酸在水溶液中的自组装形成稳定的超分子三角棱镜及其与DNA的复合（环烯= 1,4,7,10-四氮杂环十二烷）的设计与合成
2. Supramolecular Complexes Formed by the Self-assembly of Hydrophobic Bis(Zn2+-cyclen) Complexes, Copper, and Di- or Triimide Units for the Hydrolysis of Phosphate Mono- and Diesters in Two-Phase Solvent Systems (Cyclen=1,4,7,10-Tetraazacyclododecane) [J] . Yosuke Hisamatsu, Yuya Miyazawa, Kakeru Yoneda, Chemical and Pharmaceutical Bulletin . 2016,第5期

机译：由疏水性双（Zn 2 + -cycln）配合物，铜和二或三酰亚胺单元自组装形成的超分子配合物，用于在两相溶剂体系中水解磷酸单酯和二酯（周期数= 1,4,7,10-四氮杂环十二烷）
3. Selective hydrolysis of phosphate monoester by a supramolecular phosphatase formed by the self-assembly of a Bis(Zn~(2+)-cyclen) complex, cyanuric acid, and copper in an aqueous solution (cyclen = 1,4,7,10- tetraazacyclododecane) [J] . Zulkefeli M., Suzuki A., Shiro M., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2011,第20期

机译：Bis（Zn〜（2 +）-cycln）配合物，氰尿酸和铜在水溶液中的自组装形成的超分子磷酸酶对磷酸单酯的选择性水解（循环数= 1,4,7,10-四氮环十二烷）
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机译：基于异钴（III）和镍（II）双萜烯吡啶配合物的金属 - 超分子二嵌段共聚物
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6. Supramolecular Chemistry And Self-assembly Special Feature: Anion-templated self-assembly of tetrahedral cage complexes ofcobalt(II) with bridging ligands containing two bidentatepyrazolyl-pyridine binding sites [O] . Rowena L. Paul, Zöe R. Bell, John C. Jeffery, 2002

机译：超分子化学和自组装特征：阴离子模板的四面体笼状配合物自组装含两个二齿桥联配体的钴（II）吡唑基-吡啶结合位点
7. New supramolecular trigonal prisms from zinc(II)– 1,4,7,10-tetraazacyclododecane (cyclen) complexes and trithiocyanurate in aqueous solution [O] . Aoki, Shin, Zulkefeli, Mohd, Shiro, Motoo, 2002

机译：新型超分子三角棱镜锌（II）– 1,4,7,10-四氮杂十二烷（环）络合物和水溶液中的三硫氰尿酸酯

Supramolecular Chemistry And Self-assembly Special Feature: New supramolecular trigonal prisms fromzinc(II)– 14710-tetraazacyclododecane (cyclen) complexes andtrithiocyanurate in aqueous solution

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