首页> 美国卫生研究院文献>Proceedings of the National Academy of Sciences of the United States of America >Supramolecular Chemistry And Self-assembly Special Feature: Hydrogen bonding and perhalometallate ions: A supramolecularsynthetic strategy for new inorganic materials
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Supramolecular Chemistry And Self-assembly Special Feature: Hydrogen bonding and perhalometallate ions: A supramolecularsynthetic strategy for new inorganic materials

机译:超分子化学和自组装特征:氢键和全卤代金属离子:超分子新型无机材料的合成策略

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摘要

A synthetic strategy for constructing ionic hydrogen-bonded materials by combining perhalometallate anions with cations able to serve as hydrogen bond donors is presented. The approach is based on identification of well defined hydrogen bond acceptor sites on the anions by a combination of experimental and theoretical approaches. Selective population of these sites by hydrogen bond donors has the potential to afford organized crystalline arrays in one, two, or three dimensions. The approach is applicable to a wide range of metal centers.
机译:提出了通过将全卤代金属盐阴离子与能够充当氢键供体的阳离子相结合来构建离子氢键材料的合成策略。该方法是通过结合实验和理论方法,确定阴离子上明确定义的氢键受体位置。氢键供体对这些位点的选择性填充具有提供一维,二维或三维结构的晶体阵列的潜力。该方法适用于各种金属中心。

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