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Variety of valence bond states formed of frustrated spins on triangular lattices based on a two-level system Pd(dmit)2

机译:基于两级系统Pd(dmit)2的三角形晶格上沮丧的自旋形成的价键态的多样性

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摘要

Recent studies on the physical properties of the triangular system based on the Pd(dmit)2 salts (dmit=1,3-dithiole-2-thione-4,5-dithiolate) are reviewed. Quantum chemical architectures of the Pd(dmit)2 molecule and its dimer are introduced with emphasis on the strong dimerization of a two-level system, which provides unique physical properties of the salts. The magnetic properties are outlined in view of the magneto-structural correlation specific to the frustrated spin systems. Some newly discovered ground states and their origins are discussed, for which the valence bond formation plays a key role. Among them, the two-level structure is crucial for the novel charge-separated state found in two salts. The valence bond ordering, similar to the spin-Peierls transition, has been found in a two-dimensional frustrated spin system. The physical aspects and possible relation to the pressure-induced superconductivity are discussed.
机译:综述了基于Pd(dmit)2盐(dmit = 1,3-dithiole-2-thione-4,5-dithiolate)的三角体系的物理性质的最新研究。介绍了Pd(dmit)2分子及其二聚体的量子化学结构,重点是两级体系的强二聚作用,该体系提供了盐的独特物理性质。鉴于受挫的自旋系统特有的磁结构相关性,概述了磁性能。讨论了一些新发现的基态及其起源,在这些基态中价键的形成起着关键作用。其中,两级结构对于在两种盐中发现的新型电荷分离态至关重要。在二维受阻自旋系统中发现了类似于自旋-Peierls过渡的价键有序。讨论了物理方面以及与压力引起的超导的可能关系。

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