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Multilevel Tunnelling Systems and Fractal Clustering in the Low-Temperature Mixed Alkali-Silicate Glasses

机译:低温混合碱硅酸盐玻璃的多层隧道系统和分形聚类

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摘要

The thermal and dielectric anomalies of window-type glasses at low temperatures (T < 1 K) are rather successfully explained by the two-level systems (2LS) standard tunneling model (STM). However, the magnetic effects discovered in the multisilicate glasses in recent times, magnetic effects in the organic glasses, and also some older data from mixed (SiO2)1−x(K2O)x and (SiO2)1−x(Na2O)x glasses indicate the need for a suitable extension of the 2LS-STM. We show that—not only for the magnetic effects, but also for the mixed glasses in the absence of a field—the right extension of the 2LS-STM is provided by the (anomalous) multilevel tunnelling systems (ATS) proposed by one of us for multicomponent amorphous solids. Though a secondary type of TS, different from the standard 2LS, was invoked long ago already, we clarify their physical origin and mathematical description and show that their contribution considerably improves the agreement with the experimental data. In spite of dealing with low-temperature properties, our work impinges on the structure and statistical physics of glasses at all temperatures.
机译:通过两级系统(2LS)标准隧穿模型(STM),成功地解释了低温(T <1 K)时窗型玻璃的热和介电异常。但是,近来在多硅酸盐玻璃中发现的磁效应,有机玻璃中的磁效应,以及来自(SiO2)1-x(K2O)x和(SiO2)1-x(Na2O)x混合玻璃的一些较旧的数据表示需要适当扩展2LS-STM。我们证明,不仅对于电磁效应,而且对于不存在场的混合玻璃,我们的一个人提出的(异常)多层隧道系统(ATS)都为2LS-STM提供了正确的扩展。用于多组分无定形固体。尽管很早以前就已经调用了不同于标准2LS的第二种TS,但我们弄清了它们的物理起源和数学描述,并表明它们的贡献大大改善了与实验数据的一致性。尽管要处理低温属性,但我们的工作会影响所有温度下玻璃的结构和统计物理学。

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