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The highly selective oxidation of cyclohexane to cyclohexanone and cyclohexanol over VAlPO4 berlinite by oxygen under atmospheric pressure

机译：大气压下氧在VAlPO4柏林铁矿上将环己烷高度选择性氧化为环己酮和环己醇

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BackgroundThe oxidation of cyclohexane under mild conditions occupies an important position in the chemical industry. A few soluble transition metals were widely used as homogeneous catalysts in the industrial oxidation of cyclohexane. Because heterogeneous catalysts are more manageable than homogeneous catalysts as regards separation and recycling, in our study, we hydrothermally synthesized and used pure berlinite (AlPO4) and vanadium-incorporated berlinite (VAlPO4) as heterogeneous catalysts in the selective oxidation of cyclohexane with molecular oxygen under atmospheric pressure. The catalysts were characterized by means of by XRD, FT-IR, XPS and SEM. Various influencing factors, such as the kind of solvents, reaction temperature, and reaction time were investigated systematically.

机译：背景技术在温和条件下环己烷的氧化在化学工业中占有重要地位。几种可溶性过渡金属被广泛用作环己烷工业氧化中的均相催化剂。由于在分离和回收方面，非均相催化剂比均相催化剂更易于管理，因此在我们的研究中，我们水热合成并使用纯柏林铁（AlPO4）和钒结合的柏林铁（VAlPO4）作为非均相催化剂，在分子氧条件下用分子氧选择性氧化环己烷气压。通过XRD，FT-IR，XPS和SEM对催化剂进行表征。系统地研究了溶剂种类，反应温度，反应时间等多种影响因素。

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期刊名称 BMC Chemistry
作者
Yun Hong; Dalei Sun; Yanxiong Fang;
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作者单位

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年(卷),期 2018(12),-1
年度 2018
页码 36
总页数 9
原文格式 PDF
正文语种
中图分类生化遗传学;生化药理学;
关键词
Oxidation Cyclohexane Heterogeneous catalyst Berlinite;

机译：氧化;环己烷;非均相催化剂;柏林石;

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专利

1. The highly selective oxidation of cyclohexane to cyclohexanone and cyclohexanol over VAlPO 4 berlinite by oxygen under atmospheric pressure [J] . Yun Hong, Dalei Sun, Yanxiong Fang Chemistry central journal . 2018,第1期

机译：大气压下氧在VAlPO 4 berinite上高选择性地将环己烷氧化为环己酮和环己醇
2. Vanadium Oxides Supported on Zinc Oxide Nanoparticles for Selective Oxidation of Cyclohexane to Cyclohexanone and Cyclohexanol [J] . Advances in Environmental Biology . 2014,第16期

机译：氧化锌纳米颗粒上负载的钒氧化物，用于将环己烷选择性氧化为环己酮和环己醇
3. All nanoparticles supported on Cr-based metal-organic framework as bimetallic catalyst for selective oxidation of cyclohexane to cyclohexanone and cyclohexanol [J] . Zhiguo Sun, Gang Li, Liping Liu Catalysis Communications . 2012,第Null期

机译：所有纳米颗粒均作为双金属催化剂负载在Cr基金属有机骨架上，用于将环己烷选择性氧化为环己酮和环己醇
4. Photocatalytic Oxidation of Cyclohexane into Cyclohexanol and Cyclohexanone over TiO2/TS-1 System by Molecular Oxygen [C] . Global conference of young Chinese scientists on catalysis science and technology . 1995

机译：分子氧对TiO2 / TS-1系统上的环己烷和环己酮的光催化氧化
5. Design and use of recombinant whole cell systems in organic chemistry: Synthetic applications of cyclohexanone monooxygenase, cytochromes P450 and epoxide hydrolases. [D] . Martinez, Carlos Alberto. 2000

机译：重组全细胞系统在有机化学中的设计和使用：环己酮单加氧酶，细胞色素P450和环氧化物水解酶的合成应用。
6. Optimization of Cyclohexanol and Cyclohexanone Yield in the Photocatalytic Oxofunctionalization of Cyclohexane over Degussa P-25 under Visible Light [O] . Adolfo Henríquez, Victoria Melin, Nataly Moreno, 2019

机译：可见光下Degussa P-25在环己烷光催化氧化官能化中环己醇和环己酮收率的优化
7. Catalytic oxidation of cyclohexane to cyclohexanol and cyclohexanone over Co3O4 nanocrystals with molecular oxygen [O] . Zhou LP, Xu J, Miao H, 2005

机译：Catalytic oxidation of cyclohexane to cyclohexanol and cyclohexanone over Co3O4 nanocrystals with molecular oxygen

The highly selective oxidation of cyclohexane to cyclohexanone and cyclohexanol over VAlPO4 berlinite by oxygen under atmospheric pressure

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