首页> 美国卫生研究院文献>Acta Crystallographica Section E: Crystallographic Communications >Bisbis(22′-bipyridine-κ2 NN′)chloridocopper(II) bis(μ-26-pyridinedicarboxylato)-κ4 O 2NO 6:O 6;κ4 O 2:O 2NO 6-bisaquadichloridobismuthate(III) pentahydrate

【2h】

Bisbis(22′-bipyridine-κ2 NN′)chloridocopper(II) bis(μ-26-pyridinedicarboxylato)-κ4 O 2NO 6:O 6;κ4 O 2:O 2NO 6-bisaquadichloridobismuthate(III) pentahydrate

机译：Bis bis（22-联吡啶-κ2 NN）氯化铜（II）双（μ-26-吡啶二羧酸基）-κ4 Ø 2NO 6：O 6; k4 Ø 2：O 2NO 6-双水合二氯铋铋（III）五水合物

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In the title compound, [CuCl(C10H8N2)2]2[Bi2Cl4(C7H3NO4)2(H2O)2]·5H2O, the dianion [Bi2Cl4(C₇H₃NO₄)₂(H₂O)₂]²⁻ is located about an inversion center. The Cu^II atom of the cation is coordinated by four N atoms of the two chelating 2,2′-bypyridine ligands and one Cl⁻ ion, completing a distorted trigonal–bipyramidal coordination environment. In the anion, each Bi^III atom is seven-coordinate and is bonded to a tridentate pyridine-2,6-dicarboxylate ligand, a water molecule, two chloride ions and a bridging carboxylate O atom of another carboxylate ligand. The coordination geometry of Bi^III is distorted pentagonal–bipyramidal with the Cl⁻ ions located in axial positions. The structure of the dianion is additionally stabilized by an intramolecular O—H⋯O hydrogen bond between the coordinated water molecule and carboxylate O atom. In the crystal, O—H⋯O hydrogen bonds occur . The H atoms of the solvent water molecules could not be located.

机译：在标题化合物[CuCl（C10H8N2）2] 2 [Bi2Cl4（C7H3NO4）2（H2O）2]·5H2O中，二价阴离子[Bi2Cl4（C _{7 H _{3 NO _{4 ）_{2 （H _{2 O）_{2 ] ^{2-位于关于反转中心。阳离子的Cu ^{II 原子由两个螯合的2,2'-吡啶吡啶配体的四个N原子和一个Cl ^{-离子配位，完成了扭曲的三角锥型协调环境。在阴离子中，每个Bi ^{III 原子为七个配位基，并键合至三齿吡啶-2,6-二羧酸酯配体，水分子，两个氯离子和另一个羧酸酯的桥连羧酸酯O原子配体。 Bi ^{III 的配位几何是五边形-双锥体，而Cl ^{-离子位于轴向位置。二价阴离子的结构还通过配位的水分子和羧酸根O原子之间的分子内OH-OH氢键来稳定。在晶体中，发生OH-氢键。找不到溶剂水分子的H原子。}}}}}}}}}}}}

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期刊名称 Acta Crystallographica Section E: Crystallographic Communications
作者
Hong-Wei Wang; Wan-Lan Liu; Yu-Quan Feng;
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作者单位

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年(卷),期 2011(67),Pt 12
年度 2011
页码 m1651
总页数 11
原文格式 PDF
正文语种
中图分类生化遗传学;生化药理学;
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1. catena-Poly[4,4′-bipyridinium [[tetraaqua(pyridine-2,6-dicarboxylato-κ3O2,N,O6)cerate(III)]-μ-pyridine-2,6-dicarboxylato-κ4O2:O2′,N,O6-[(pyridine-2,6-dicarboxylato-κ3O2,N,O6)cerate(III)]-μ-pyridine-2,6-dicarboxylato-κ4O2,N,O6:O6′] pentahydrate] [J] . Aghabozorg H., Mirzaei M., Notash B., Acta Crystallographica Section E: Crystallographic Communications . 2011,第3期

机译：catena-Poly [4,4'-Bipyridinium [[tetraaqua（pyridine-2,6-dicarboxylato-κ3O2，N，O6）cerate（III）]-μ-吡啶-2,6-dicarboxylato-κ4O2：O2'，N ，O6-[（吡啶-2,6-二羧基-κ3O2，N，O6）铈（III）]-μ-吡啶-2,6-二羧基-κ4O2，N，O6：O6']五水合物]
2. Bis(2,3-diaminopyridinium) bis(μ-pyridine-2,6-dicarboxylato)-κ4O2,N,O6:O6;κ4O2:O2,N,O6-bis[aqua(pyridine-2,6-dicarboxylato-κ3O2,N,O6)bismuthate(III)] tetrahydrate [J] . Agah A.A., Aghabozorg H., Kazemi S., Acta Crystallographica Section E: Crystallographic Communications . 2011,第3期

机译：双（2,3-二氨基吡啶）双（μ-吡啶-2,6-二羧酸）-κ4O2，N，O6：O6;κ4O2：O2，N，O6-双[水（吡啶-2,6-二羧酸-κ3O2），N，O6）铋酸盐（III）四水合物
3. Tetra-μ-aqua-octaaquabis(μ-4-chloropyridine-2,6-dicarboxylato)bis(4-chloropyridine-2,6-dicarboxylato)tricobalt(II)disodium(I) bis[triaquabis(4-chloropyridine-2,6-dicarboxylato)cobalt(II)] hexahydrate [J] . Balof S., Holder A.A., Moody L.M., Acta Crystallographica Section E: Crystallographic Communications . 2008,第1期

机译：四（--4-吡啶2,6-二羧酸4-吡啶基）二（4-氯吡啶-2,6-二羧酸吡啶）（II）二钠（I）bis [三（4-氯吡啶-2，（6-二羧酸盐）钴（II）]六水合物
4. Bis(23-diaminopyridinium) bis(μ-pyridine-26-dicarboxylato)-κ4 O 2NO 6:O 6;κ4 O 2:O 2NO 6-bisaqua(pyridine-26-dicarboxylato-κ3 O 2NO 6)bismuthate(III) tetrahydrate [O] . Hossein Aghabozorg, Shokoofeh Kazemi, Ali Akbar Agah, 2011

机译：双（23-二氨基吡啶鎓）双（μ-吡啶-26-二羧基吡啶）-κ4 Ø 2NO 6：O 6; k4 Ø 2：O 2NO 6-双水（吡啶-26-二羧基-κ3 Ø 2NO 6）铋酸盐（III）四水合物
5. Bis[bis(2,2′-bipyridine-κ2 N,N′)chloridocopper(II)] bis(μ-2,6-pyridinedicarboxylato)-κ4 O 2,N,O 6:O 6;κ4 O 2:O 2,N,O 6-bis[aquadichloridobismuthate(III)] pentahydrate [O] . Wang, Hong-Wei, Liu, Wan-Lan, Feng, Yu-Quan 2011

机译：Bis [bis（2,2'-联吡啶-κ2 N，N'）氯化铜（II）]双（μ-2,6-吡啶二羧酸基）-κ4 Ø 2，N，O 6：O 6; k4 Ø 2：O 2，N，O 6-双[水合二氯铋铋（III）]五水合物

Bisbis­(22′-bipyridine-κ2 NN′)chloridocopper(II) bis­(μ-26-pyridine­dicarboxyl­ato)-κ4 O 2NO 6:O 6;κ4 O 2:O 2NO 6-bis­aqua­dichloridobismuthate(III) penta­hydrate

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Bisbis(22′-bipyridine-κ2 NN′)chloridocopper(II) bis(μ-26-pyridinedicarboxylato)-κ4 O 2NO 6:O 6;κ4 O 2:O 2NO 6-bisaquadichloridobismuthate(III) pentahydrate