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A general derivation and quantification of the third law of thermodynamics

机译:热力学第三定律的一般推导和量化

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摘要

The most accepted version of the third law of thermodynamics, the unattainability principle, states that any process cannot reach absolute zero temperature in a finite number of steps and within a finite time. Here, we provide a derivation of the principle that applies to arbitrary cooling processes, even those exploiting the laws of quantum mechanics or involving an infinite-dimensional reservoir. We quantify the resources needed to cool a system to any temperature, and translate these resources into the minimal time or number of steps, by considering the notion of a thermal machine that obeys similar restrictions to universal computers. We generally find that the obtainable temperature can scale as an inverse power of the cooling time. Our results also clarify the connection between two versions of the third law (the unattainability principle and the heat theorem), and place ultimate bounds on the speed at which information can be erased.
机译:热力学第三定律的最公认版本,即不可达到性原理,指出任何过程都不能在有限的步骤和有限的时间内达到绝对零温度。在这里,我们提供了适用于任意冷却过程的原理的推导,甚至包括那些利用量子力学定律或涉及无限维储库的过程。通过考虑与通用计算机相似的热机概念,我们量化了将系统冷却至任何温度所需的资源,并将这些资源转换为最少的时间或步骤数。我们通常发现,可获得的温度可以与冷却时间成反比。我们的结果还阐明了第三定律的两个版本之间的联系(不可达到性原理和热定理),并为擦除信息的速度设定了最终界限。

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