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Thermal properties of Zn2(C8H4O4)2•C6H12N2 metal-organic framework compound and mirror symmetry violation of dabco molecules

机译：Zn2（C8H4O4）2•C6H12N2金属-有机骨架化合物的热性质和镜像对称性破坏dabco分子

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Thermal properties of Zn2(C8H4O4)2•C6H12N2 metal-organic framework compound at 8–300 K suggest the possibility of subbarrier tunnelling transitions between left-twisted (S) and right-twisted (R) forms of C6H12N2 dabco molecules with D3 point symmetry. The data agree with those obtained for the temperature behavior of nuclear spin-lattice relaxation times. It is shown that there is a temperature range where the transitions are stopped. Therefore, Zn2(C8H4O4)₂•C₆H₁₂N₂ and related compounds are interesting objects to study the effect of spontaneous mirror-symmetry breaking and stabilization of chiral isomeric molecules in solids at low temperatures.

机译：Zn2（C8H4O4）2•C6H12N2金属-有机骨架化合物在8–300 K的热性质表明，在具有D3点对称性的C6H12N2 dabco分子的左旋（S）和右旋（R）形式之间存在亚势垒隧穿转变的可能性。数据与获得的核自旋晶格弛豫时间的温度行为数据一致。结果表明存在一个温度范围，在该温度范围内过渡停止。因此，Zn2（C8H4O4）_{2 •C _{6 H _{12 N _{2 及其相关化合物是有趣的研究对象。低温下自然自发镜像对称破坏和稳定手性异构体的效果。}}}}

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期刊名称 Scientific Reports
作者
Svetlana G. Kozlova; Svyatoslav P. Gabuda;
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年(卷),期 -1(7),-1
年度 -1
页码 11505
总页数 5
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1. Behavior of the heat capacity at second-order phase transitions in the [Zn-2(C8H4O4)(2) center dot C6H12N2] metal-organic framework compound [J] . Kozlova S. G. JETP Letters . 2016,第4期

机译：[Zn-2（C8H4O4）（2）中心点C6H12N2]金属-有机骨架化合物在二级相变处的热容行为
2. Phase transitions in a metal-organic coordination polymer: [Zn-2(C8H4O4)(2)(C6H12N2)] with guest molecules. Thermal effects and molecular mobility [J] . Kozlova Svetlana G., Pishchur Denis P., Dybtsev Danil N. Phase Transitions . 2017,第6期

机译：金属 - 有机配位聚合物中的相转变：具有访客分子的[Zn-2（C8H4O4）（2）（2）（C6H12N2）]。热效应和分子迁移率
3. Sorption of benzene vapors to flexible metal-organic framework [Zn2(bdc)2(dabco)] [J] . Elissa A. Ukraintseva, Andrey Yu. Manakov, Denis G. Samsonenko Journal of Inclusion Phenomena and Macrocyclic Chemistry . 2013,第1a4期

机译：苯蒸气吸附到柔性金属有机骨架[Zn2（bdc）2（dabco）]
4. In-situ FT-IR Investigation of the Decomposition of Nano Zn4O(C8H4O4)_3 Metal-Organic Framework [C] . Peifu Cheng, Yun Hang Hu ACS National Meeting Exhibition . 2013

机译：原位FT-IR对纳米Zn4O（C8H4O4）_3金属有机框架分解的研究
5. Measurements of Thermal Properties of Phonon Bridge Adhesion Layers, Nanogaps and Metal-organic Frameworks Using Frequency-domain Thermoreflectance (FDTR) [D] . Jeong, Minyoung. 2018

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6. Nitrogen-Rich Energetic Metal-Organic Framework: Synthesis Structure Properties and Thermal Behaviors of Pb(II) Complex Based on NN-Bis(1H-tetrazole-5-yl)-Amine [O] . Qiangqiang Liu, Bo Jin, Qingchun Zhang, 2016

机译：富氮的高能金属有机骨架：基于NN-双（1H-四唑-5-基）-胺的Pb（II）配合物的合成结构性质和热行为
7. Thermal properties of Zn2(C8H4O4)2•C6H12N2 metal-organic framework compound and mirror symmetry violation of dabco molecules [O] . Svetlana G. Kozlova, Svyatoslav P. Gabuda 2017

机译：Zn2（C8H4O4）的热性能2•C6H12N2金属 - 有机框架化合物和镜像对称侵犯DABCO分子

Thermal properties of Zn2(C8H4O4)2•C6H12N2 metal-organic framework compound and mirror symmetry violation of dabco molecules

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