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Pentiptycene-Based Luminescent Cu (II) MOF Exhibiting Selective Gas Adsorption and Unprecedentedly High-Sensitivity Detection of Nitroaromatic Compounds (NACs)

机译：基于戊二烯的发光铜（II）MOF表现出选择性气体吸附和硝基芳族化合物（NAC）的超高灵敏度检测

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The assembly of a fluorescent pentiptycene-based ligand with copper ion resulted in the formation of a 3D porous metal-organic framework (>UPC-21) based on well-known paddlewheel SBUs. >UPC-21 exhibits selective adsorption of CO2 over CH4 and N2 at 273 K and 295 K, C2H2 over CH4 at 273 K. The most significant performance of >UPC-21 is its highly efficient detection of NACs such as 4-NP, 1,4-DNB, NB, and 1,3-DNB with the calculated quenching constants, Ksv, being 3.097 × 10⁶, 1.406 × 10⁶, 4.420 × 10⁵, and 1.498 × 10⁵M⁻¹ for 4-NP, 1,4-DNB, NB, 1,3-DNB, respectively, which keeps a record on the fluorescence detection of NACs. This is the first porous Cu(II) MOF that exhibits fluorescent detection of NACs with high sensitivities.

机译：荧光五萜烯基配体与铜离子的组装导致形成基于众所周知的桨轮SBU的3D多孔金属-有机骨架（> UPC-21 ）。 > UPC-21 在273 K和295 K时对CH4和N2有选择性的吸附，在273 K时CH2H2对CH4有选择性的吸附。> UPC-21 的最显着性能是计算出的淬灭常数Ksv为3.0974-×10 ^{6 ，1.406×10 <的NAC，例如4-NP，1,4-DNB，NB和1,3-DNB的高效检测sup> 6 ，4.420×10 ^{5 和1.498×10 ^{5 M ^{-1 对于4-NP，1,4 -DNB，NB，1,3-DNB，分别记录了NAC的荧光检测。这是第一个以高灵敏度对NAC进行荧光检测的多孔Cu（II）MOF。}}}}

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期刊名称 Scientific Reports
作者
Minghui Zhang; Liangliang Zhang; Zhenyu Xiao; Qinhui Zhang; Rongming Wang; Fangna Dai; Daofeng Sun;
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年(卷),期 -1(6),-1
年度 -1
页码 20672
总页数 10
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1. Pentiptycene-Based Luminescent Cu (II) MOF Exhibiting Selective Gas Adsorption and Unprecedentedly High-Sensitivity Detection of Nitroaromatic Compounds (NACs) [J] . Minghui Zhang, Liangliang Zhang, Zhenyu Xiao, Scientific reports. . 2016,第1期

机译：基于五庚啶的发光Cu（II）MOF表现出选择性气体吸附和前所未有的硝基芳族化合物的高灵敏度检测（NACS）
2. A novel luminescent cadmium(II) MOFs exhibiting a sensitive and selective detection of trace amounts of nitroaromatics with excellent recyclability [J] . Sun Zan, Bao Yuting, Wang Chong, Inorganica Chimica Acta . 2019,第期

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3. Luminescent Terbium-Organic Framework Exhibiting Selective Sensing of Nitroaromatic Compounds (NACs) [J] . Wang Wen, Yang Jie, Wang Rongming, Crystal growth & design . 2015,第6期

机译：发光的-有机骨架对硝基芳族化合物（NAC）的选择性传感
4. Selective and Sensitive Detection of Nitroaromatic Compounds by Fluorescent Europium Based Metal Organic Framework [C] . Sonia Bamnia, Girish C. Mohanta, Sudipta S. Pal International Conference on Optics and Electro-Optics . 2021

机译：荧光铕金属有机骨架的选择性和敏感检测硝基芳族化合物
5. Synthesis and phtoluminescence study of Microporous Metal Organic Frameworks (MMOFs) for sensing and detection of nitroexplosives and aromatic compounds [D] . Pramanik, Sanhita 2011

机译：微孔金属有机骨架（MMOF）的合成和光致发光研究，用于感测和检测硝基炸药和芳香族化合物
6. A luminescent Zn-MOF exhibiting high water stability: selective detection of Cr(VI) ion and treatment activity on sepsis [O] . Ying Wan, Xu-Mei Chen, Qian Zhang, 2021

机译：发光Zn-MOF具有高水位稳定性：选择性检测败血症的Cr（VI）离子和治疗活性
7. Pentiptycene-Based Luminescent Cu (II) MOF Exhibiting Selective Gas Adsorption and Unprecedentedly High-Sensitivity Detection of Nitroaromatic Compounds (NACs) [O] . Minghui Zhang, Liangliang Zhang, Zhenyu Xiao, 2016

机译：基于五庚啶的发光Cu（II）MOF表现出选择性气体吸附和前所未有的硝基芳族化合物的高灵敏度检测（NACS）
8. Tandem Mass Spectrometer for the Detection of Nitroaromatic Compounds and Other Electronegative Species in Ambient Air [R] . Glish, G. L., McLuckey, S. A., McKown, H. S. 1985

机译：用于检测环境空气中硝基芳香族化合物和其他电负性物质的串联质谱仪

Pentiptycene-Based Luminescent Cu (II) MOF Exhibiting Selective Gas Adsorption and Unprecedentedly High-Sensitivity Detection of Nitroaromatic Compounds (NACs)

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