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Thin-film ‘Thermal Well’ Emitters and Absorbers for High-Efficiency Thermophotovoltaics

机译:薄膜热阱发射器和吸收器用于高效热光伏

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摘要

A new approach is introduced to significantly improve the performance of thermophotovoltaic (TPV) systems using low-dimensional thermal emitters and photovoltaic (PV) cells. By reducing the thickness of both the emitter and the PV cell, strong spectral selectivity in thermal emission and absorption can be achieved by confining photons in trapped waveguide modes inside the thin-films that act as thermal analogs to quantum wells. Simultaneously, photo-excited carriers travel shorter distances across the thin-films reducing bulk recombination losses resulting in a lower saturation current in the PV cell. We predict a TPV efficiency enhancement with near-field coupling between the thermal emitter and the PV cell up to 38.7% using a thin-film germanium (Ge) emitter at 1000 K and an ultra-thin gallium antimonide (GaSb) cell supported by perfect back reflectors separated by 100 nm. Even in the far-field limit, the efficiency is predicted to reach 31.5%, which is over an order of magnitude higher than the Shockley Queisser limit of 1.6% for a bulk GaSb cell and a blackbody emitter at 1000 K. The proposed design approach does not require nanoscale patterning of the emitter and PV cell surfaces, but instead offers a simple low-cost solution to improve the performance of thermophotovoltaic systems.
机译:引入了一种新方法,以使用低维热发射器和光伏(PV)电池显着提高热电(TPV)系统的性能。通过减小发射极和PV电池的厚度,可以通过将光子限制在用作量子阱的热模拟物的薄膜内的捕获波导模式中来实现强的热发射和吸收光谱选择性。同时,光激发载流子跨薄膜移动的距离更短,从而减少了本体复合损失,从而导致PV电池中的饱和电流降低。我们使用1000 K的薄膜锗(Ge)发射极和完美支持的超薄锑化镓(GaSb)电池,预测热发射器与PV电池之间的近场耦合将使TPV效率提高38.7%。后反射器相隔100纳米。即使在远场限制下,效率也有望达到31.5%,比在1000 K的GaSb电池和黑体发射极的Shockley Queisser限制1.6%高出一个数量级。不需要对发射极和PV电池表面进行纳米级图案化,而是提供了一种简单的低成本解决方案来提高热电光伏系统的性能。

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