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A Highly Controllable Electrochemical Anodization Process to Fabricate Porous Anodic Aluminum Oxide Membranes

机译:制备多孔阳极氧化铝膜的高度可控的电化学阳极氧化工艺

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摘要

Due to the broad applications of porous alumina nanostructures, research on fabrication of anodized aluminum oxide (AAO) with nanoporous structure has triggered enormous attention. While fabrication of highly ordered nanoporous AAO with tunable geometric features has been widely reported, it is known that its growth rate can be easily affected by the fluctuation of process conditions such as acid concentration and temperature during electrochemical anodization process. To fabricate AAO with various geometric parameters, particularly, to realize precise control over pore depth for scientific research and commercial applications, a controllable fabrication process is essential. In this work, we revealed a linear correlation between the integrated electric charge flow throughout the circuit in the stable anodization process and the growth thickness of AAO membranes. With this understanding, we developed a facile approach to precisely control the growth process of the membranes. It was found that this approach is applicable in a large voltage range, and it may be extended to anodization of other metal materials such as Ti as well.Electronic supplementary materialThe online version of this article (doi:10.1186/s11671-015-1202-y) contains supplementary material, which is available to authorized users.
机译:由于多孔氧化铝纳米结构的广泛应用,具有多孔结构的阳极氧化铝的制备研究引起了极大的关注。尽管已经广泛报道了具有可调整的几何特征的高度有序的纳米多孔AAO的制备,但是众所周知,其生长速率很容易受到电化学阳极氧化过程中诸如酸浓度和温度之类的工艺条件波动的影响。为了制造具有各种几何参数的AAO,特别是要实现对孔深度的精确控制以用于科学研究和商业应用,可控的制造过程是必不可少的。在这项工作中,我们揭示了在稳定的阳极氧化过程中,整个电路中的积分电荷流与AAO膜的生长厚度之间存在线性关系。基于这种理解,我们开发了一种简便的方法来精确控制膜的生长过程。已发现这种方法适用于较大的电压范围,并且可以扩展到其他金属材料(例如Ti)的阳极氧化。电子补充材料本文的在线版本(doi:10.1186 / s11671-015-1202- y)包含补充材料,授权用户可以使用。

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