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Data on removal kinetics of pharmaceutical compounds artificial sweeteners and perfluoroalkyl substances from water using a passive treatment system containing zero-valent iron and biochar

机译:使用包含零价铁和生物炭的被动处理系统从水中去除药物化合物人造甜味剂和全氟烷基物质的动力学数据

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摘要

The data presented in this paper relate to the research paper “Removal of pharmaceutical compounds, artificial sweeteners, and perfluoroalkyl substances from water using a passive treatment system containing zero-valent iron and biochar” [1]. Four columns packed with different ratios of reactive media, including silica sand (SS), zero-valent iron (ZVI), and biochar (BC), were evaluated for simultaneous removal of 14 emerging contaminants from water. The target emerging contaminants included eight pharmaceuticals (carbamazepine, caffeine, sulfamethoxazole, 3,4-methylenedioxyamphetamine, 3,4-methylenedioxymethamphetamine, ibuprofen, gemfibrozil, and naproxen), four artificial sweeteners (acesulfame-K, sucralose, saccharin, and cyclamate), and two perfluoroalkyl substances (perfluorooctanoic acid and perfluorooctane sulfonic acid). The samples for target contaminant analysis were collected from the influent, effluent, and profile (along the flow direction) ports of each column. The removal data (concentration vs. residence time) for each target contaminant were fitted to the first-order (exponential decay equation) or zero-order (linear equation) model using SigmaPlot. The removal rate, removal rate constant (kobs), mass normalized rate constant (kM), surface area normalized rate constant (kSA, specific reaction rate constant), and half-life (t0.5) of target contaminants in Columns ZVI, BC, and (ZVI + BC) were calculated and summarized in this dataset.
机译:本文提供的数据与研究论文“使用包含零价铁和生物炭的被动处理系统从水中去除药物化合物,人工甜味剂和全氟烷基物质”有关[1]。评估了四根装有不同比例反应介质(包括硅砂(SS),零价铁(ZVI)和生物炭(BC))的色谱柱,用于从水中同时去除14种新兴污染物。目标新兴污染物包括八种药物(卡马西平,咖啡因,磺胺甲恶唑,3,4-亚甲基二氧苯丙胺,3,4-亚甲基二氧甲苯丙胺,布洛芬,吉非贝齐和萘普生),四种人造甜味剂(乙酰磺胺酸钾,三氯蔗糖,糖精和甜蜜素)和两种全氟烷基物质(全氟辛酸和全氟辛烷磺酸)。从每个色谱柱的进水口,出水口和轮廓(沿流向)端口收集用于目标污染物分析的样品。使用SigmaPlot将每种目标污染物的去除数据(浓度与停留时间)拟合为一阶(指数衰减方程)或零阶(线性方程)模型。 ZVI,BC列中目标污染物的去除速率,去除速率常数(kobs),质量归一化速率常数(kM),表面积归一化速率常数(kSA,比反应速率常数)和半衰期(t0.5)和(ZVI + BC)并在此数据集中进行汇总。

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