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Colloidal Self-Assembly of Inorganic Nanocrystals into Superlattice Thin-Films and Multiscale Nanostructures

机译:无机纳米晶体的胶体自组装成超晶格薄膜和多尺度纳米结构

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摘要

The self-assembly of colloidal inorganic nanocrystals (NCs) offers tremendous potential for the design of solution-processed multi-functional inorganic thin-films or nanostructures. To date, the self-assembly of various inorganic NCs, such as plasmonic metal, metal oxide, quantum dots, magnetics, and dielectrics, are reported to form single, binary, and even ternary superlattices with long-range orientational and positional order over a large area. In addition, the controlled coupling between NC building blocks in the highly ordered superlattices gives rise to novel collective properties, providing unique optical, magnetic, electronic, and catalytic properties. In this review, we introduce the self-assembly of inorganic NCs and the experimental process to form single and multicomponent superlattices, and we also describe the fabrication of multiscale NC superlattices with anisotropic NC building blocks, thin-film patterning, and the supracrystal formation of superlattice structures.
机译:胶态无机纳米晶体(NCs)的自组装为溶液加工的多功能无机薄膜或纳米结构的设计提供了巨大的潜力。迄今为止,据报道,各种无机NC的自组装,例如等离激元金属,金属氧化物,量子点,磁性和电介质,形成了一个,二元甚至三元的超晶格,它们在a上具有长距离的取向和位置顺序。大面积。此外,高度有序超晶格中NC构件之间的受控耦合产生了新颖的集合特性,提供了独特的光学,磁性,电子和催化特性。在这篇综述中,我们介绍了无机NC的自组装以及形成单组分和多组分超晶格的实验过程,并且还描述了具有各向异性NC构造块,薄膜图案化和超晶格形成的多尺度NC超晶格的制备。超晶格结构。

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