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Exchange Phenomena in the Electron Paramagnetic Resonance Spectra of the Nitroxyl and Trityl Radicals: Multifunctional Spectroscopy and Imaging of Local Chemical Microenvironment

机译：硝基和三苯甲基自由基的电子顺磁共振光谱中的交换现象：多功能光谱和局部化学微环境的成像。

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摘要

This Feature overviews the basic principles of using stable organic radicals involved in reversible exchange processes as functional paramagnetic probes. We demonstrate that these probes in combination with electron paramagnetic resonance (EPR)-based spectroscopy and imaging techniques provide analytical tools for quantitative mapping of critical parameters of local chemical microenvironment. The Feature is written to be understandable to people who are laymen to the EPR field in anticipation of future progress and broad application of these tools in biological systems, especially in vivo, over the next years.

机译：本功能概述了使用可逆交换过程中涉及的稳定有机自由基作为顺磁性探针的基本原理。我们证明，这些探针与基于电子顺磁共振（EPR）的光谱学和成像技术相结合，为定量映射局部化学微环境的关键参数提供了分析工具。编写该功能对于EPR领域的外行人来说是可以理解的，因为他们期望在未来几年内这些工具在生物系统（尤其是体内）中的发展和广泛应用。

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期刊名称 other
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Valery V. Khramtsov; Andrey A. Bobko; Mark Tseytlin; Benoit Driesschaert;
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年(卷),期 -1(89),9
年度 -1
页码 4758–4771
总页数 39
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1. Exchange Phenomena in the Electron Paramagnetic Resonance Spectra of the Nitroxyl and Trityl Radicals: Multifunctional Spectroscopy and Imaging of Local Chemical Microenvironment [J] . Khramtsov Valery V., Bobko Andrey A., Tseytlin Mark, Analytical chemistry . 2017,第9期

机译：Nitroxyl和Trityl基团的电子顺磁共振光谱中的交换现象：局部化学微环境的多功能光谱和成像
2. Trityl Radicals as Persistent Dual Function pH and Oxygen Probes for in Vivo Electron Paramagnetic Resonance Spectroscopy and Imaging: Concept and Experiment [J] . Andrey A. Bobko, Ilirian Dhimitruka, Jay L. Zweier, Journal of the American Chemical Society . 2007,第23期

机译：三苯甲基自由基作为体内双顺式pH和氧探针用于体内电子顺磁共振波谱和成像的概念和实验
3. A Time-Resolved Electron Paramagnetic Resonance Investigation of the Spin Exchange and Chemical Interactions of Reactive Free Radicals with Isotopically Symmetric (~(14)N-X-~(14)N) and Isotopically Asymmetric (~(14)N-X-~(15)N) Nitroxyl Biradicals [J] . Elena Sartori, Igor V. Khudyakov, Xuegong Lei, Journal of the American Chemical Society . 2007,第25期

机译：同位素对称（〜（14）NX-〜（14）N）和同位素非对称（〜（14）NX-〜（15）N）的自由基的自旋交换和化学相互作用的时间分辨电子顺磁共振研究硝基氧自由基
4. Electron Spin Resonance Spectra of Nitroxyl Radicals [C] . Edith Botek, Natalia Zarycz, Benoit Champagne, International Conference of Computational Methods in Sciences and Engineering . 2014

机译：电子旋转硝基自由基的共振谱
5. The structure of benzimidazole-3-oxide-1-oxyl radicals in a toluene matrix: A combined advanced electron paramagnetic resonance spectroscopy and quantum mechanics calculation study [D] . Cheng, Yo-Yuan 2011

机译：甲苯基质中苯并咪唑-3-氧化物-1-氧基的结构：先进的电子顺磁共振光谱和量子力学计算的组合研究
6. Fourier Transform EPR Spectroscopy of Trityl Radicals for Multifunctional Assessment of Chemical Microenvironment [O] . Dr. Andrey A. Bobko, Dr. Ilirian Dhimitruka, Prof. Dr. Jay L. Zweier, -1

机译：三苯甲基自由基的傅里叶变换EPR光谱用于化学微环境的多功能评估
7. Trityl Radicals as Persistent Dual Function pH and Oxygen Probes for in Vivo Electron Paramagnetic Resonance Spectroscopy and Imaging: Concept and Experiment [O] . -1

机译：TRITYL激进作为持续的双函数pH和氧气探针在体内电子顺磁共振光谱和成像：概念和实验
8. Electron Paramagnetic Resonance Measurements of Photochemical Radical Production in Humic Substances. 1. Effects of O2 and Charge on Radical Scavenging by Nitroxides [R] . Blough, N. V. 1988

机译：腐殖质光化学自由基生成的电子顺磁共振测量。 1.氧气和电荷对氮氧自由基清除自由基的影响

Exchange Phenomena in the Electron Paramagnetic Resonance Spectra of the Nitroxyl and Trityl Radicals: Multifunctional Spectroscopy and Imaging of Local Chemical Microenvironment

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