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Airborne Particulate Matter (PM) filter analysis and modeling by Total reflection X-Ray Fluorescence (TXRF) and X-Ray Standing Wave (XSW)

机译:空气颗粒物质(PM)通过全反射X射线荧光(TXRF)和X射线常设波(XSW)的滤波器分析和建模

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摘要

This work is presented as an improvement of a recently introduced method for airborne particulate matter (PM) filter analysis []. X-ray Standing Wave (XSW) and Total reflection X-Ray Fluorescence (TXRF) were performed with a new dedicated laboratory instrumentation. The main advantage of performing both XSW and TXRF, is the possibility to distinguish the nature of the sample: if it is a small droplet dry residue, a thin film like or a bulk sample; and to select the angle of total reflection to make TXRF measurements. Finally, the possibility to switch the X-ray source allows to measure with more accuracy lighter and heavier elements (with a a change in X-ray anode, for example from Mo to Cu). The aim of the present study is to lay the theoretical foundation of the new proposed method for airborne PM filters quantitative analysis improving the accuracy and efficiency of quantification by means of an external standard. The theoretical model presented and discussed demonstrated that airborne PM filters can be considered as thin layers. A set of reference samples is prepared in laboratory and used to obtain a calibration curve. Our results demonstrate that the proposed method for quantitative analysis of air PM filters is affordable and reliable without the necessity to digest filters to obtain quantitative chemical analysis, and that the use of XRW improve the accuracy of TXRF analysis.

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