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Dynamic Cylindrical Assembly of Triblock Copolymers by a Hierarchical Process of Covalent and Supramolecular Interactions

机译:三嵌段共聚物的动态圆柱大会通过共价和超分子相互作用的分级过程

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摘要

We have developed a hierarchical process that combines linear triblock copolymers into concentric globular sub-units through strong chemical bonds and is followed by their supramolecular assembly via weak non-covalent interactions to afford one-dimensionally-assembled, dynamic cylindrical nanostructures. The molecular brush architecture forces triblock copolymers to adopt some intramolecular interactions within confined frameworks and then drives their intermolecular interactions in the mixtures of organic solvent and water. In contrast, the triblock copolymers, when not pre-connected into the molecular brush architectures, organize only into globular assemblies.

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