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Studies directed toward the synthesis of the massileunicellins. 2

机译：研究指向massileunicellins的合成。 2

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The fully substituted hydroisobenzofuran core of the massileunicellins containing 8 contiguous stereocenters was prepared in 12 steps from (S)-(+)-carvone. Noteworthy elements of the synthesis include a one-step oxidative rearrangement/epoxidation, a novel stereoselective directed reduction of a keto diol, and a directed hydrogenation of a congested tetrasubstituted alkene.

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Yonghai Chai; Zonghong Mou; Matthias C. McIntosh;
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年(卷),期 -1(45),16
年度 -1
页码 3269–3272
总页数 9
原文格式 PDF
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Studies directed toward the synthesis of the massileunicellins. 2

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