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Acetylene weak bands at 2.5 μm from intracavity Cr2+:ZnSe laser absorption observed with time-resolved Fourier transform spectroscopy

机译:时间分辨傅立叶变换光谱法观察腔内Cr2 +:ZnSe激光吸收后2.5μm处的乙炔弱带

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摘要

The spectral dynamics of a mid-infrared multimode Cr2+:ZnSe laser located in a vacuum sealed chamber containing acetylene at low pressure is analyzed by a stepping-mode high-resolution time-resolved Fourier transform interferometer. Doppler-limited absorption spectra of C2H2 in natural isotopic abundance are recorded around 4000 cm−1 with kilometric absorption path lengths and sensitivities better than 3 10−8 cm−1. Two cold bands are newly identified and assigned to the ν1+ν41 and ν3+ν51 transitions of 12C13CH2. The ν1+ν51 band of 12C2HD and fourteen 12C2H2 bands are observed, among which for the first time ν2+2ν42+ν5−1.
机译:用步进模式高分辨率时间分辨傅里叶变换干涉仪分析了位于低压含乙炔的真空密封室内的中红外多模态Cr 2 + :ZnSe激光器的光谱动力学。在约4000 cm -1 处记录了自然同位素丰度中C2H2的多普勒限制吸收光谱,其千米吸收路径长度和灵敏度优于3 10 −8 cm - 1 。新确定了两个冷带,并将它们分配给 12 C 13 1 和ν3+ν5 1 过渡。 sup> CH2。观察到 12 C2HD的ν1+ν5 1 波段和14个 12 C2H2波段,其中第一次出现ν2+2ν4 2 +ν5 -1

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