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Molar Ratio Effect of Sodium to Chloride Ions on the Electrochemical Corrosion of Alloy 600 and SA508 in HCl + NaOH Mixtures

机译:钠与氯离子的摩尔比对HCl + NaOH混合物中600和SA508合金的电化学腐蚀

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摘要

This study aims to investigate the molar ratio effect of sodium to chloride ions on the corrosion of an Alloy 600 steam generator tube and an SA508 tubesheet material. The corrosion behavior was evaluated in solutions with three different molar ratios of sodium to chloride ions using a potentiodynamic polarization method. The corrosion potentials and corrosion rates of both the two materials were significantly decreased as the molar ratio increased from 0.1 to 10. Therefore, it is recommended that the molar ratio control to a value of 1 is beneficial only when the crevice chemistry has a low molar ratio with an acidic pH. The corrosion potentials and corrosion rates were little affected by the total sodium and chloride ion concentrations. SA508 acted as an anode and its corrosion rate was accelerated by galvanic coupling with Alloy 600.
机译:这项研究的目的是研究钠与氯离子的摩尔比对合金600蒸汽发生器管和SA508管板材料腐蚀的影响。使用电位动力学极化法在钠与氯离子的三种不同摩尔比的溶液中评估腐蚀行为。当摩尔比从0.1增加到10时,两种材料的腐蚀电位和腐蚀速率均显着降低。因此,建议仅当缝隙化学摩尔比较低时,将摩尔比控制为1是有益的。酸性pH的比例。钠和氯离子的总浓度几乎不影响腐蚀电位和腐蚀速率。 SA508用作阳极,通过与Alloy 600的电流偶合来加速其腐蚀速率。

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