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Optical Structural and Crystal Defects Characterizations of Dip Synthesized (Fe-Ni) Co-Doped ZnO Thin Films

机译:浸渍合成(Fe-Ni)共掺杂ZnO薄膜的光学结构和晶体缺陷表征

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摘要

Sol-gel technique is used to synthesize as-grown zinc oxide (ZnO) and iron-nickel (Fe-Ni) co-doped ZnO thin films deposited on glass substrates using dip coating technique. The structural properties and crystal imperfections of as-prepared thin films are investigated. We performed the structural analysis of films using X-ray diffraction (XRD). The XRD analysis reveal that the as-prepared films exhibit wurtzite structure. Furthermore, XRD-line profile analysis is performed to study the correlation between structural properties and imperfections of the nanocomposite thin films. The crystallite size and microstrains parameters are predicted using the Williamson–Hall method. We found that the crystallites size increases as the co-doped (Fe-Ni) concentration is increased. However, microstrains of the nanocomposite films decreases as (Fe-Ni) concentration is increased. The optical properties of the (Fe-Ni) co-doped nanocomposite films are investigated by performing UV-Vis (250 nm–700 nm) spectrophotometer measurements. We found that as the (Fe-Ni) concentration level is steadily increased, transmittance of the undoped ZnO thin films is decreased. Remarkably, refractive index of undoped ZnO thin films is found to exhibit values extending from 1.55 to1.88 that would increase as (Fe-Ni) concentration is increased.
机译:溶胶-凝胶技术用于通过浸涂技术合成沉积在玻璃基板上的已生长的氧化锌(ZnO)和铁镍(Fe-Ni)共掺杂的ZnO薄膜。研究了所制备薄膜的结构特性和晶体缺陷。我们使用X射线衍射(XRD)对薄膜进行了结构分析。 XRD分析表明,所制备的膜具有纤锌矿结构。此外,进行XRD线轮廓分析以研究纳米复合薄膜的结构性质和缺陷之间的相关性。晶粒尺寸和微应变参数是使用Williamson-Hall方法预测的。我们发现,随着共掺杂(Fe-Ni)浓度的增加,微晶尺寸也随之增加。然而,随着(Fe-Ni)浓度的增加,纳米复合膜的微应变降低。 (Fe-Ni)共掺杂纳米复合薄膜的光学性质通过执行UV-Vis(250 nm–700 nm)分光光度计测量来研究。我们发现,随着(Fe-Ni)浓度水平的不断提高,未掺杂ZnO薄膜的透射率会降低。显着地,发现未掺杂的ZnO薄膜的折射率显示出从1.55到1.88的值,该值将随着(Fe-Ni)浓度的增加而增加。

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