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A Novel Au@Cu2O-Ag Ternary Nanocomposite with Highly Efficient Catalytic Performance: Towards Rapid Reduction of Methyl Orange Under Dark Condition

机译:具有高效催化性能的新型Au @ Cu2O-Ag三元纳米复合材料:在黑暗条件下快速还原甲基橙

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摘要

Au@Cu O core-shell nanocomposites (NCs) were synthesized by reducing copper nitrate on Au colloids with hydrazine. The thickness of the Cu O shells could be varied by adjusting the molar ratios of Au: Cu. The results showed that the thickness of Cu O shells played a crucial role in the catalytic activity of Au@Cu O NCs under dark condition. The Au@Cu O-Ag ternary NCs were further prepared by a simple galvanic replacement reaction method. Moreover, the surface features were revealed by TEM, XRD, XPS, and UV–Vis techniques. Compared with Au@Cu O NCs, the ternary Au@Cu O-Ag NCs had an excellent catalytic performance. The degradation of methyl orange (MO) catalyzed by Au@Cu O-Ag NCs was achieved within 4 min. The mechanism study proved that the synergistic effects of Au@Cu O-Ag NCs and sodium borohydride facilitated the degradation of MO. Hence, the designed Au@Cu O-Ag NCs with high catalytic efficiency and good stability are expected to be the ideal environmental nanocatalysts for the degradation of dye pollutants in wastewater.
机译:通过用肼还原Au胶体上的硝酸铜来合成Au @ Cu O核壳纳米复合材料(NCs)。可以通过调节Au∶Cu的摩尔比来改变Cu O壳的厚度。结果表明,在黑暗条件下,Cu O壳的厚度对Au @ Cu O NCs的催化活性起着至关重要的作用。通过简单的电置换反应方法进一步制备了Au @ Cu O-Ag三元NC。此外,通过TEM,XRD,XPS和UV-Vis技术揭示了表面特征。与Au @ Cu O-NC NCs相比,三元Au @ Cu O-Ag NCs具有优异的催化性能。 Au @ Cu O-Ag NCs催化降解甲基橙(MO)的时间为4分钟。机理研究证明,Au @ Cu O-Ag NCs与硼氢化钠的协同作用促进了MO的降解。因此,设计的具有高催化效率和良好稳定性的Au @ Cu O-Ag NCs有望成为降解废水中染料污染物的理想环境纳米催化剂。

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