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A Potassium Ion-Exchanged Glass Optical Waveguide Sensor Locally Coated with a Crystal Violet-SiO2 Gel Film for Real-Time Detection of Organophosphorus Pesticides Simulant

机译:钾离子交换玻璃光波导传感器局部涂覆有结晶紫-SiO2凝胶膜用于实时检测有机磷农药模拟物

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摘要

An optical waveguide (OWG) sensor was developed for real-time detection of diethyl chlorophosphate (DCP) vapor, which is a typical simulant for organophosphorus pesticides and chemical weapon agents. Silica gel, crystal violet (CV), and potassium ion-exchange (PIE) OWG were used to fabricate the sensor’s device. In the real-time detection of the DCP vapor, the volume fraction of DCP vapor was recorded to be as low as 1.68 × 10 . Moreover, the detection mechanism of CV-SiO gel film coated the PIE OWG sensor for DCP, which was evaluated by absorption spectra. These results demonstrated that the change of output light intensity of the OWG sensor significantly increased with the augment of the DCP concentration. Repeatability as well as selectivity of the sensors were tested using 0.042 × 10 and 26.32 × 10 volume fraction of the DCP vapor. No clear interference with the DCP detection was observed in the presence of other common solvents (e.g., acetone, methanol, dichloromethane, dimethylsulfoxide, and tetrahydrofuran), benzene series (e.g., benzene, toluene, chlorobenzene, and aniline), phosphorus-containing reagents (e.g., dimethyl methylphosphonate and trimethyl phosphate), acid, and basic gas (e.g., acetic acid and 25% ammonium hydroxide), which demonstrates that the OWG sensor could provide real-time, fast, and accurate measurement results for the detection of DCP.
机译:开发了用于实时检测氯磷酸二乙酯(DCP)蒸气的光波导(OWG)传感器,该物质是有机磷农药和化学武器剂的典型模拟物。硅胶,结晶紫(CV)和钾离子交换(PIE)OWG用于制造传感器的设备。在DCP蒸气的实时检测中,DCP蒸气的体积分数被记录为低至1.68×10。此外,CV-SiO凝胶膜的检测机理覆盖了用于DCP的PIE OWG传感器,并通过吸收光谱对其进行了评估。这些结果表明,随着DCP浓度的增加,OWG传感器的输出光强度的变化显着增加。使用0.042×10和26.32×10体积分数的DCP蒸气测试了传感器的可重复性和选择性。在存在其他常用溶剂(例如丙酮,甲醇,二氯甲烷,二甲基亚砜和四氢呋喃),苯系列(例如苯,甲苯,氯苯和苯胺),含磷试剂的情况下,未观察到对DCP检测的明显干扰。 (例如,甲基磷酸二甲酯和磷酸三甲酯),酸和碱性气体(例如,乙酸和25%的氢氧化铵),这表明OWG传感器可以提供实时,快速和准确的测量结果以检测DCP 。

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