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Titanium Dioxide-Coated Zinc Oxide Nanorods as an Efficient Photoelectrode in Dye-Sensitized Solar Cells

机译:二氧化钛涂覆的氧化锌纳米棒作为染料敏化太阳能电池的有效光电极

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摘要

Well-arrayed zinc oxide nanorods applied as photoelectrodes for dye-sensitized solar cells were synthesized on an aluminum-doped zinc oxide substrate by the multi-annealing method. In order to improve the chemical stability and surface-to-volume ratio of photoanodes in dye-sensitized solar cells, the synthesized zinc oxide nanorods were coated with pure anatase phase titanium dioxide film using a novel mist chemical vapor deposition method. The effects of the titanium dioxide film on the morphological, structural, optical, and photovoltaic properties of zinc oxide–titanium dioxide core–shell nanorods were investigated. It was found that the diameter and surface-to-volume ratio of zinc oxide nanorods were significantly increased by coating them with titanium dioxide thin film. The power conversion efficiency of dye-sensitized solar cells was improved from 1.31% to 2.68% by coating titanium dioxide film onto the surface of zinc oxide nanorods.
机译:通过多退火方法在掺杂铝掺杂的氧化锌基底上合成施加为染料敏化太阳能电池的光电氧化锌纳米棒。为了提高染料敏化太阳能电池的光阳极的化学稳定性和表面对体积比,使用新型雾化学气相沉积方法用纯锐钛矿相相钛二氧化钛涂覆合成的氧化锌纳米棒。研究了二氧化钛膜对二氧化钛二氧化钛核壳纳米棒的形态学,结构,光学和光伏性能的影响。发现通过用二氧化钛薄膜涂覆氧化锌纳米棒的直径和表面对体积比显着增加。通过将二氧化钛膜涂覆到氧化锌纳米棒的表面上,将染料敏化太阳能电池的功率转换效率从1.31%提高到2.68%。

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