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Large‐Area Virus Coated Ultrathin Colorimetric Sensors with a Highly Lossy Resonant Promoter for Enhanced Chromaticity

机译:大面积病毒用高损伤的共振促进剂涂覆超型比色传感器用于增强色度

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摘要

Acclimatable colors in response to environmental stimuli, which are naturally endowed with some living things, can provide an opportunity for humans to recognize hazardous substances without taking empirical risks. Despite efforts to create artificial responsive colors, realistic applications in everyday life require an immediate/distinct colorimetric realization with wide chromatic selectivity. A dynamically responsive virus (M‐13 phage)‐based changeable coloring strategy is presented with a highly lossy resonant promoter (HLRP). An ultrathin M‐13 phage layer for rapid response to external stimuli displays colorimetric behavior, even in its subtle swelling with strong resonances on HLRP, which is modeled using the complex effective refractive index. Optimal designs of HLRP for several material combinations allow selective chromatic responsivity from the corresponding wide color palette without modification of the dynamic responsive layer. As a practical demonstration, the spatially designed colorimetric indicator, which is insensitive/sensitive to external stimuli, provides an intuitive perception of environmental changes with hidden/revealed patterns. Furthermore, the proposed colorimetric sensor is tested by exposure to various volatile organic chemicals and endocrine disrupting chemicals for versatile detectability, and is fabricated in a wafer‐scale sample for large‐area scalability.
机译:适应于环境刺激的适应性颜色,这些颜色自然赋予一些生物,可以为人类提供机会,以便在不采取经验风险的情况下识别有害物质。尽管努力创造人工敏感颜色,但日常生活中的现实应用需要立即/不同的比色,具有宽的色谱选择性。动态响应的病毒(M-13噬菌体)基于可变的可变着色策略,具有高度损失的共振启动子(HLRP)。超薄M-13噬菌体层,用于快速响应外部刺激,显示比色行为,即使在其对HLRP上具有强大共振的微妙肿胀,使用复杂的有效折射率建模。用于多种材料组合的HLRP的最佳设计允许来自相应的宽调色板的选择性色调,而无需修改动态响应层。作为实际演示,空间设计的比色指示器对外部刺激不敏感/敏感,提供了对隐藏/揭示的图案的环境变化的直观感知。此外,通过暴露于各种挥发性有机化学品和内分泌的化学物质来测试所提出的比色传感器以进行多功能可检测性,并在晶片级样品中制造以进行大面积可扩展性。

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