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Modeling and Optimization of Pollutants Removal during Simultaneous Adsorption onto Activated Carbon with Advanced Oxidation in Aqueous Environment

机译:污染物在同时吸附到活性炭中的污染物去除的建模与优化水环境中晚期氧化

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摘要

The paper presents the results of studies on the modeling and optimization of organic pollutant removal from an aqueous solution in the course of simultaneous adsorption onto activated carbons with varied physical characteristics and oxidation using H2O2. The methodology for determining the models used for predicting the sorption and catalytic parameters in the process was presented. The analysis of the influence of the sorption and catalytic parameters of activated carbons as well as the oxidizer dose on the removal dynamics of organic dyes-phenol red and crystal violet-was carried out based on the designated empirical models. The obtained results confirm the influence of specific surface area (S) of the activated carbon and oxidizer dose on the values of the reaction rate constants related to the removal of pollutants from the solution in a simultaneous process. It was observed that the lower the specific surface area of carbon (S), the greater the influence of the oxidizer on the removal of pollutants from the solution. The proposed model, used for optimization of parameters in a simultaneous process, enables to analyze the effect of selected sorbents as well as the type and dose of the applied oxidizer on the pollutant removal efficiency. The practical application of models will enable to optimize the selection of a sorbent and oxidizer used simultaneously for a given group of pollutants and thus reduce the process costs.
机译:本文介绍了在通过同时吸附到具有变化的物理特性和使用H 2 O 2的物理特性和氧化过程中从水溶液中取出的有机污染物的模拟和优化从水溶液中去除的研究结果。提出了用于确定用于预测该过程中吸附和催化参数的模型的方法。基于指定的经验模型,进行了对活性碳活性碳的吸附和催化参数对有机染料 - 酚红色和晶体紫的去除动力学影响的分析。得到的结果证实了活性炭和氧化剂剂量的比表面积对与同时过程中溶液中除去污染物相关的反应速率常数的值的影响。观察到碳的比表面积越低,氧化剂对从溶液中除去污染物的影响越大。所提出的模型,用于在同时工艺中进行参数的优化,可以分析选定吸附剂的效果以及所施加的氧化剂的类型和剂量对污染物去除效率。模型的实际应用将使针对给定污染物组同时使用的吸附剂和氧化剂的选择能够优化,从而降低过程成本。

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