首页> 美国卫生研究院文献>Membranes >Mixed-Matrix Membranes Comprising of Polysulfone and Porous UiO-66 Zeolite 4A and Their Combination: Preparation Removal of Humic Acid and Antifouling Properties
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Mixed-Matrix Membranes Comprising of Polysulfone and Porous UiO-66 Zeolite 4A and Their Combination: Preparation Removal of Humic Acid and Antifouling Properties

机译:混合基质膜包括聚砜和多孔UIO-66沸石4a及其组合:制备去除腐殖酸和防污性能

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摘要

High-performance Mixed-Matrix Membranes (MMMs) comprising of two kinds of porous fillers UiO-66 and Zeolite 4Aand their combination were fabricated with polysulfone (PSf) polymer matrix. For the very first time, UiO-66 and Zeolite 4A were jointly used as nanofillers in MMMs with the objective of complimenting synergistic effects. The individual and complimentary effects of nanofillers were investigated on membrane morphology and performance, pure water flux, humic acid rejection, static humic acid adsorption, and antifouling properties of membranes. Scanning Electron Microscopy (SEM) analysis of membranes confirmed that all MMMs possessed wider macrovoids with higher nanofiller loadings than neat PSf membranes and the MMMs (PSf/UiO-66 and PSf/Zeolite 4A-UiO-66) showed tendency of agglomeration with high nanofiller loadings (1 wt% and 2 wt%). All MMMs exhibited better hydrophilicity and lower static humic acid adsorption than neat PSf membranes. Pure water flux of MMMs was higher than neat PSf membranes but the tradeoff between permeability and selectivity was witnessed in the MMMs with single nanofiller. However, MMMs with combined nanofillers (PSf/Zeolite 4A-UiO-66) showed no such tradeoff, and an increase in both permeability and selectivity was achieved. All MMMs with lower nanofiller loadings (0.5 wt% and 1 wt%) showed improved flux recovery. PSf/Zeolite 4A-UiO-66 (0.5 wt%) membranes showed the superior antifouling properties without sacrificing permeability and selectivity.
机译:用聚砜(PSF)聚合物基质制备包含两种多孔填料UIO-66和沸石4A和它们的组合的高性能混合基质膜(MMMS)。为了第一次,UIO-66和沸石4a在MMMS中共同用作纳米填充物,其目的是赞美协同效应。研究了纳米填充物的个体和互补效果对膜形态和性能,纯净的水通量,腐殖酸排斥,静态腐殖酸吸附和膜的防污性能。扫描电子显微镜(SEM)分析膜的分析证实,所有MMMS都具有比整齐的PSF膜和MMMS(PSF / UIO-66和PSF /沸石4A-UIO-66)具有更高纳米填充载荷的较宽的宏烷基(PSF / UIO-66和PSF /沸石4A-UIO-66)显示了高纳米汞的倾向载荷(1wt%和2wt%)。所有MMMS都表现出比整齐的PSF膜更好的亲水性和更低的静态腐殖酸吸附。 MMM的纯净水通量高于整齐的PSF膜,但在具有单纳米甲填充物的MMM中见证了渗透性和选择性之间的折衷。然而,具有组合纳米填充物(PSF /沸石4A-UIO-66)的MMM没有显示出这样的权衡,并且实现了渗透性和选择性的增加。具有下纳米填充载荷(0.5wt%和1wt%)的所有MMM显示出改善的磁通回收。 PSF /沸石4A-UIO-66(0.5wt%)膜显示出优异的防污性能而不牺牲渗透性和选择性。

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