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Effects of Catalyst Pretreatment on Carbon Nanotube Synthesis from Methane Using Thin Stainless-Steel Foil as Catalyst by Chemical Vapor Deposition Method

机译:催化剂预处理对甲烷碳纳米管合成的影响薄不锈钢箔作为催化剂通过化学气相沉积法

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摘要

Synthesis of carbon nanotubes (CNTs) was carried out using methane as a carbon source via the chemical vapor deposition (CVD) method. A thin stainless-steel foil was used as catalyst for CNT growth. Our results revealed that pretreatment step of the stainless-steel foil as a catalyst plays an important role in CNT formation. In our experiments, a catalyst pretreatment temperature of 850 °C or 950 °C was found to facilitate the creation of Fe- and Cr-rich particles are active sites on the foil surface, leading to CNT formation. It is noted that the size of metallic particles after pretreatment is closely related to the diameter of the synthesized CNTs. It is interesting that a shorter catalyst pretreatment brings the growth of semiconducting typed CNTs while a longer pretreatment creates metallic CNTs. This finding might lead to a process for improving the quality of CNTs grown on steel foil as catalyst.
机译:通过化学气相沉积(CVD)方法,使用甲烷作为碳源进行碳纳米管(CNT)的合成。薄不锈钢箔用作CNT生长的催化剂。我们的研究结果表明,不锈钢箔作为催化剂的预处理步骤在CNT形成中起重要作用。在我们的实验中,发现850℃或950℃的催化剂预处理温度促进富含Fe和Cr的颗粒是箔表面上的活性位点,导致CNT形成。应注意,预处理后金属颗粒的尺寸与合成的CNT的直径密切相关。有趣的是,较短的催化剂预处理使半导体类型的CNT的生长产生了较长的预处理,产生金属CNT。这一发现可能导致改善钢箔在催化剂上生长的CNT质量的过程。

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