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Dataset on aqueous solid-liquid extraction of gossypol from defatted cottonseed in acidic medium using green solvent its kinetics and thermodynamics study and mass transfer effects

机译:使用绿色溶剂其动力学和热力学研究和传质效应来自酸性培养基中脱脂棉籽水溶液水溶液的数据集

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摘要

Extraction of gossypol from cottonseed is essentially required to produce cottonseed free from gossypol for animal feed and or human applications. The focus of the present research was to determine the percentage gossypol extraction after extracting the defatted cottonseed using environment friendly green solvent ethanol-water (95:5 v/v) acidified with 0.5 M oxalic acid. The cottonseed samples were taken according to the fixed solvent to seed ratio and were extracted in batch process using round bottom flasks maintained at required temperatures for different extraction times ranging from 5 to 180 mins. After extraction the samples were filtered and dried and subjected to total gossypol analysis using BIS method. One factor at a time (OFAT) experimental design was employed to optimize the different process parameters like acid type and concentration, solvent to seed ratio, temperature and contact time. The obtained data was studied for analysis of kinetics of extraction using three different kinetic models, calculation of activation energy, evaluating values of kinetic parameters and thermodynamic parameters. The data was also analyzed for evaluation of mass transfer effects viz. liquid film diffusion and internal solid diffusion and calculation of diffusion rate constants for the extraction of gossypol from cottonseed. The present dataset demonstrated the analysis of experimental data for determining the type of kinetics, thermodynamic parameters and mass transfer effects of the solvent extraction for future researchers.
机译:从棉籽中提取棉酚基本上需要生产棉籽免于动物饲料和或人类应用的棉花糖。本研究的重点是在用0.5M草酸酸化的环境友好的绿色溶剂乙醇 - 水(95:5V / v)酸化后,确定脱脂棉籽萃取百分比。根据固定溶剂对种子比采集棉籽样品,并使用维持在所需温度的圆底烧瓶中的分批过程中提取,用于不同的萃取时间为5-180分钟。萃取后,将样品过滤并干燥并使用BIS法进行全古脂醇分析。使用时间(OFAT)实验设计的一个因素,以优化酸类型和浓度等不同的工艺参数,溶剂与种子比,温度和接触时间。研究了所获得的数据,用于使用三种不同的动力学模型进行提取动力学,激活能量计算,进行动力学参数评估值和热力学参数。还分析了数据以评估传质效应viz。液膜扩散和内部固体扩散和扩散速率常数的计算从棉籽中提取棉酚。目前的数据集证明了用于确定溶剂提取的动力学类型,热力学参数和传质效应的实验数据的分析。

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