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Effect of the Na2O–Nb2O5–P2O5 glass additive on the structure dielectric and energy storage performances of sodium niobate ceramics

机译:Na2O-Nb2O5-P2O5玻璃添加剂对铌酸钠陶瓷结构介电和能量储存性能的影响

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摘要

A phosphate glass Na2O–Nb2O5–P2O5 (NPP) is incorporated into NaNbO3 (NN) ceramics to examine its impact on the density, rearrangement of structural units, dielectric and energy storage features of the elaborated composites. The sodium niobate ceramic (NN) is prepared using the solid state process, whereas, the Na2O–Nb2O5–P2O5 (NPP) glasses are produced using the method of conventional melt quenching. The glass (NPP) is added to the ceramic (NN) according to the composition (100-x) NN-xNNP; (x = 0, 2.5, 5, and 7.5 %wt). The developed composites are denoted as NN-Gx where x represents the content of glass in %wt. The appropriate sintering temperature for the glass-ceramic composites was measured based on the density measurements. It was found that with the addition of glass, their density was decreased and their fritting at lower temperatures was enhanced. The obtained SST for all composites is about 900 °C. After the densification stage, Raman spectroscopy, X-ray Diffraction, Granulo-laser analysis, and scanning electron microscopy are examined to study the structural approach and the morphology of sintered NN-Gx composites. The NN-G5 composite was found to have a fine grain microstructure that was uniform. The dielectric features of the composite revealed that at ambient temperature the NN-G5 had the greatest dielectric constant. The energy storage performance of the composite was investigated from the P-E plots and the parameters of energy storage. Based on the obtained results, it was concluded that incorporating up to 5% wt. of NNP glass in sodium niobate ceramics positively affects their dielectric and energy storage performances.
机译:将磷酸盐玻璃Na2O-Nb2O5-P2O5(NPP)掺入纳米3(NN)陶瓷中,以检查其对胚胎组合物的结构单元的密度,重排,介质和能量存储特征的影响。使用固态方法制备铌酸钠陶瓷(NN),而使用常规熔体淬火的方法制备Na 2 O-Nb2O5-P2O5(NPP)玻璃。根据组合物(100-X)NN-XNNP将玻璃(NPP)加入陶瓷(NN)中; (x = 0,2.5,5和7.5%wt)。开发的复合材料表示为NN-GX,其中X表示%wt的玻璃含量。基于密度测量测量玻璃陶瓷复合材料的适当烧结温度。发现,随着添加玻璃,它们的密度降低,并提高了较低温度下的塑料。所有复合材料的获得的SST约为900℃。在致密化阶段,拉曼光谱学,X射线衍射,颗粒激光分析和扫描电子显微镜检查以研究烧结NN-GX复合材料的结构方法和形态。发现NN-G5复合材料具有均匀的细粒微观结构。复合材料的介电特征显示,在环境温度下,NN-G5具有最大的介电常数。从P-E的图和能量存储参数研究了复合材料的能量存储性能。基于所得的结果,得出结论,掺入高达5%的重量。铌酸钠陶瓷中的NNP玻璃积极影响它们的介质和能量存储性能。

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