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Facile and Green Synthesis of Starfruit-Like ZIF-L and Its Optimization Study

机译:淀粉样ZIF-L的容易和绿色合成及其优化研究

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摘要

Due to its excellent characteristics, zeolitic imidazole framework-L (ZIF-L) is widely used in various applications, such as drug delivery, wastewater treatments and energy storage. In the synthesis of ZIF-L, the molar ratio of ligand to metal, the reaction time and the temperature are essential parameters to produce excellent ZIF-L. In this work, ZIF-L was synthesized using a facile and green synthesis method. It was statistically investigated and optimized to obtain the best operating conditions. The optimization was carried out toward the amount of adsorbed crystal violet (CV) dye (q) as the response in the statistics. The optimal ZIF-L was obtained using a molar ratio of ligand to metal of 8.2220 for 97 min at 29 °C, where the q value of the CV adsorption onto this optimal ZIF-L reached 823.02 mg/g. The obtained ZIF-L was characterized using SEM, XRD, FTIR and TGA analyses to ensure its excellent characteristics.
机译:由于其优异的特性,沸石咪唑框架-1(ZIF-1)广泛用于各种应用,例如药物递送,废水处理和储能。在ZIF-L的合成中,配体与金属的摩尔比,反应时间和温度是产生优异ZIF-L的必要参数。在这项工作中,使用容易和绿色的合成方法合成ZIF-L.它在统计上调查和优化,以获得最佳运行条件。优化朝向吸附的晶体紫(CV)染料(Q)作为统计的反应的量进行。在29℃下使用配体与8.2220的金属的摩尔比获得最佳ZIF-L,其中CV吸附到该最佳Zif-L上的Q值达到823.02mg / g。使用SEM,XRD,FTIR和TGA分析表征所获得的ZIF-L以确保其优异的特性。

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