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Non-halogenated Ionic Liquid Dramatically Enhances Tribological Performance of Biodegradable Oils

机译:非卤离子液体显着增强了可生物降解油的摩擦学性能

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摘要

It is demonstrated that a phosphonium orthoborate ionic liquid may serve as a wear reducing additive in biodegradable oils at steel-steel surfaces in the boundary lubrication regime. Tribological tests were performed in a ball-on-three plate configuration. A set of surface characterization techniques—SEM/EDS, FIB and white light interferometry were used to characterize surfaces following the tribotests and to observe the formation of any tribofilms. 11B NMR was used to follow changes in the composition of the ionic-liquid-oil blends and to identify boron-containing decomposition products after the tribotests. The ionic liquid reduces the wear of steel surfaces by up to 92% compared to the neat oil at 90°C; it is shown that the reduction in wear can be correlated with the formation of boron enriched patches in the boundary films.
机译:结果表明,在边界润滑状态下,原硼酸phospho离子液体可作为可降解油在钢表面处的可生物降解油中发挥作用。摩擦测试是在三球板上进行的。一系列表面表征技术-SEM / EDS,FIB和白光干涉法用于表征摩擦试验后的表面并观察任何摩擦膜的形成。用 11 B NMR追踪离子-液体-油混合物的组成变化,并通过摩擦试验鉴定出含硼的分解产物。与90°C时的纯油相比,离子液体可将钢表面的磨损降低多达92%;结果表明,磨损的减少与边界膜中富硼斑块的形成有关。

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