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The Occurrence and Risks of Selected Emerging Pollutants in Drinking Water Source Areas in Henan China

机译:河南省饮用水水源地区某些新兴污染物的发生和风险

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摘要

The occurrence of organic micropollutants (OMPs) in aqueous environments has potential effects on ecological safety and human health. Three kinds of OMPs (namely, pharmaceuticals, ultraviolet (UV) filters and organophosphate esters (OPEs)) in four drinking water source areas in Henan Province of China were analyzed, and their potential risks were evaluated. Among 48 target chemicals, 37 pollutants with total concentrations ranging from 403.0 to 1751.6 ng/L were detected in water, and 13 contaminants with total concentrations from 326.0 to 1465.4 ng/g (dry weight) were observed in sediment. The aqueous pollution levels in Jiangang Reservoir and Shahe Water Source Area were higher than that in Nanwan Reservoir and Baiguishan Reservoir, while the highest total amount of pollutants in sediment was found in Baiguishan Reservoir. Compared with pharmaceuticals and UV filters, OPEs presented higher concentrations in all investigated drinking water source areas. The highest observed concentration was triphenylphosphine oxide (TPPO, 865.2 ng/L) in water and tripentyl phosphate (TPeP, 1289.8 ng/g) in sediment. Moreover, the risk quotient (RQ) analysis implies that the determined aqueous contaminants exhibited high risks to algae and invertebrates, whereas moderate risk to fish was exhibited. The health risk assessment of aqueous OMPs by means of the hazard index (HI) indicates that the risks to adults and children were negligible. These observations are expected to provide useful information for the assessment of water quality in drinking water sources in Henan, China.
机译:水性环境中有机微污染物(OMPs)的存在对生态安全和人类健康具有潜在影响。分析了河南省四个饮用水水源地的三种OMPs(即药品,紫外线过滤剂和有机磷酸酯(OPE)),并评估了其潜在风险。在48种目标化学品中,水中检出37种污染物,总浓度在403.0至1751.6 ng / L之间,在沉积物中观察到13种污染物,总浓度在326.0至1465.4 ng / g(干重)之间。建港水库和沙河水源区的水污染水平高于南湾水库和白桂山水库,而白桂山水库的沉积物中污染物总量最高。与药品和紫外线过滤剂相比,在所有调查的饮用水水源区域中,OPE的浓度更高。观察到的最高浓度是水中的三苯膦氧化物(TPPO,865.2 ng / L)和沉积物中的磷酸三戊酯(TPeP,1289.8 ng / g)。此外,风险商(RQ)分析表明,确定的水污染物对藻类和无脊椎动物具有高风险,而对鱼类则具有中等风险。通过危险指数(HI)评估水性OMP的健康风险表明,成人和儿童的风险可以忽略不计。这些观察结果有望为评估中国河南饮用水源的水质提供有用的信息。

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