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Preorganized AgI Bimetallic Precursor with Labile Diphosphorus Ligands for a Programmed Synthesis of Organometallic–Organic Hybrid Polymers

机译：带有不稳定二磷配体的预组装AgI双金属前体用于有机金属-有机杂化聚合物的程序合成

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摘要

An Ag^I dimer capped with labile organometallic diphosphorus ligands [Cp2Mo2(CO)4(η²‐P2)] (Cp=C5H5) acts as a highly pre‐organized molecular precursor to direct the construction of 1D or 2D, and 3D organometallic–organic hybrid coordination polymers upon reaction with ditopic pyridine‐based linkers. The formation of the supramolecular aggregates can be controlled by the stoichiometry of the organic molecules, and the mechanism is supported by DFT calculations.

机译：Ag ^{I 二聚体被不稳定的有机金属二磷配体[Cp2Mo2（CO）4（η^{2 -P2）]（Cp = C5H5）封端与基于对位吡啶的连接基反应后，可指导1D或2D以及3D有机金属-有机杂化配位聚合物的构建。超分子聚集体的形成可以通过有机分子的化学计量来控制，并且该机理由DFT计算来支持。}}

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期刊名称 Wiley-Blackwell Online Open
作者
Dr. Mehdi Elsayed Moussa; Dr. Michael Seidl; Dr. Gábor Balázs; Dr. Manfred Zabel; Dr. Alexander V. Virovets; Dr. Bianca Attenberger; Andrea Schreiner; Prof. Dr. Manfred Scheer;
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年(卷),期 -1(23),64
年度 -1
页码 16199–16203
总页数 5
原文格式 PDF
正文语种
中图分类
关键词
controlled synthesis diphosphorus complex hybrid coordination polymers organometallic node preorganized precursor;

机译：受控合成;二磷配合物;杂化配位聚合物;有机金属节点;预组织前体;

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专利

1. Discrete and Polymeric Organometallic‐Organic Hybrid Materials Based on the Diphosphorus Complex [Cp ₂2 Mo ₂2 (CO) ₄4 (η ^{22 ‐P ₂2 )], Cu ^{II Salts, and 2,2′‐Bipyrimidine}} [J] . Elsayed Moussa Mehdi, Attenberger Bianca, Seidl Michael, European journal of inorganic chemistry . 2017,第47期

机译：基于二磷络合物的离散和聚合物有机金属 - 有机杂化材料[Cp _{2 2 mo _{2 2（CO）_{4 4（η^{2 2 -p _{2 2），Cu i i salts和2,2'-bipyrimidine}}}}}
2. Different behavior of PDA as a preorganized ligand versus PCA ligand in constructing two inorganic-organic hybrid materials based on Keggin-type polyoxometalate [J] . Mirzaei Masoud, Eshtiagh-Hosseini Hossein, Hassanpoor Azam Inorganica Chimica Acta . 2019,第期

机译：PDA作为预组织配体的不同行为与PCA配体构建基于Keggin型聚氧酸盐的两种无机有机杂化材料
3. Synthesis and structure of new phosphine-substituted homo-and hetero-bimetallic carbonyl clusters of iron, ruthenium and nickel. Characterization of two inorganic-organometallic hybrid materials based on mesoporous SBA-15 silica [J] . Carniato F, Gatti G, Gervasio G, Inorganica Chimica Acta . 2010,第8期

机译：铁，钌和镍的新膦取代的均金属和异双金属羰基簇的合成与结构。基于中孔SBA-15二氧化硅的两种无机-有机金属杂化材料的表征
4. Two pillared three-dimensional inorganic/organic hybrid structures composed of bimetallic layers bridged by exo-bidentate ligands [C] . Long Pan, Xiaoying Huang, Jing Li Materials Research Society Symposium . 2001

机译：两个柱形三维无机/有机混合结构由由外缘二齿配体桥接的双金属层组成
5. The preparation and characterization of highly dispersed supported bimetallic catalysts from inorganic and organometallic molecular precursors. [D] . Chandler, Bert Donald. 1999

机译：由无机和有机金属分子前体制备高度分散的负载型双金属催化剂并进行表征。
6. The Diphosphorus Complex Cp2Mo2(CO)4(η2‐P2) as a Building Block for the Synthesis of Mixed‐Hybrid Coordination Polymers [O] . Mehdi Elsayed Moussa, Bianca Attenberger, Martin Fleischmann, -1

机译：二磷配合物Cp2Mo2（CO）4（η2-P2）作为合成混合杂化配位聚合物的基础
7. Preorganized Ag I Bimetallic Precursor with Labile Diphosphorus Ligands for a Programmed Synthesis of Organometallic–Organic Hybrid Polymers [O] . Mehdi Elsayed Moussa, Michael Seidl, Gábor Balázs, 2017

机译：具有不稳定二磷酸配体的预混合Ag I双金属前体，用于有机金属 - 有机杂交聚合物的编程合成

Preorganized AgI Bimetallic Precursor with Labile Diphosphorus Ligands for a Programmed Synthesis of Organometallic–Organic Hybrid Polymers

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