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Self-Assembled 2D Perovskite Layers for Efficient Printable Solar Cells

机译:自组装二维钙钛矿层,用于高效可印刷太阳能电池

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摘要

2D organic-inorganic hybrid Ruddlesden-Popper perovskites have emerged recently as candidates for the light-absorbing layer in solar cell technology due largely to their impressive operational stability compared with their 3D-perovskite counterparts. The methods reported to date for the preparation of efficient 2D perovksite layers for solar cells involve a nonscalable spin-coating step. In this work, a facile, spin-coating-free, directly scalable drop-cast method is reported for depositing precursor solutions that self-assemble into highly oriented, uniform 2D-perovskite films in air, yielding perovskite solar cells with power conversion efficiencies (PCE) of up to 14.9% (certified PCE of 14.33% +/- 0.34 at 0.078 cm(2)). This is the highest PCE to date for a solar cell with 2D-perovskite layers fabricated by nonspin-coating method. The PCEs of the cells display no evidence of degradation after storage in a nitrogen glovebox for more than 5 months. 2D-perovskite layer deposition using a slot-die process is also investigated for the first time. Perovskite solar cells fabricated using batch slot-die coating on a glass substrate or R2R slot-die coating on a flexible substrate produced PCEs of 12.5% and 8.0%, respectively.
机译:2D有机-无机混合钙钛矿型Ruddlesden-Popper钙钛矿最近已成为太阳能电池技术中光吸收层的候选材料,这主要是因为与3D钙钛矿相比,它们具有令人印象深刻的操作稳定性。迄今为止报道的用于制备用于太阳能电池的有效2D过钙钛矿层的方法涉及不可缩放的旋涂步骤。在这项工作中,报道了一种简便,无旋涂,可直接扩展的滴铸法,用于将前体溶液沉积在空气中,这些前体溶液会自组装成高度取向的均匀2D钙钛矿薄膜,从而产生具有功率转换效率的钙钛矿太阳能电池( PCE)高达14.9%(在0.078 cm(2)处的认证PCE为14.33%+/- 0.34)。这是迄今为止通过非旋涂法制造的具有2D钙钛矿层的太阳能电池的最高PCE。在氮气手套箱中存放超过5个月后,细胞的PCE没有显示出降解的迹象。还首次研究了使用狭缝模头工艺的2D钙钛矿层沉积。使用在玻璃基板上的批量狭缝模头涂层或在柔性基板上的R2R狭缝模头涂层制造的钙钛矿太阳能电池,其PCE分别为12.5%和8.0%。

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  • 来源
    《Advanced energy materials》 |2019年第4期|1803258.1-1803258.9|共9页
  • 作者单位

    CSIRO Mfg, Flexible Elect Lab, Clayton, Vic 3168, Australia|Natl Ctr Nanosci & Technol, CAS Key Lab Nanosyst & Hierarch Fabricat, CAS Ctr Excellence Nanosci, Beijing 100190, Peoples R China|Univ Chinese Acad Sci, Beijing 100049, Peoples R China;

    CSIRO Mfg, Flexible Elect Lab, Clayton, Vic 3168, Australia;

    CSIRO Mfg, Flexible Elect Lab, Clayton, Vic 3168, Australia;

    Monash Univ, Dept Mat Sci & Engn, Clayton, Vic 3800, Australia;

    Monash Univ, Dept Mat Sci & Engn, Clayton, Vic 3800, Australia|ANSTO, Australian Synchrotron, 800 Blackburn Rd, Clayton, Vic 3168, Australia;

    Monash Univ, Dept Mat Sci & Engn, Clayton, Vic 3800, Australia;

    CSIRO Mfg, Flexible Elect Lab, Clayton, Vic 3168, Australia;

    Natl Ctr Nanosci & Technol, CAS Key Lab Nanosyst & Hierarch Fabricat, CAS Ctr Excellence Nanosci, Beijing 100190, Peoples R China|Univ Chinese Acad Sci, Beijing 100049, Peoples R China;

    CSIRO Mfg, Flexible Elect Lab, Clayton, Vic 3168, Australia;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    2D perovskite solar cells; drop-cast; printable solar cells; self-assembly;

    机译:二维钙钛矿太阳能电池;压铸;可印刷太阳能电池;自组装;

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