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Ultrathin 2D TiS_2 Nanosheets for High Capacity and Long-Life Sodium Ion Batteries

机译:超薄2D TIS_2纳米电池用于高容量和长寿命钠离子电池

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摘要

Sodium ion batteries are now attracting great attention, mainly because of the abundance of sodium resources and their cheap raw materials. 2D materials possess a unique structure for sodium storage. Among them, transition metal chalcogenides exhibit significant potential for rechargeable battery devices due to their tunable composition, remarkable structural stability, fast ion transport, and robust kinetics. Herein, ultrathin TiS2 nanosheets are synthesized by a shear-mixing method and exhibit outstanding cycling performance (386 mAh g(-1) after 200 cycles at 0.2 A g(-1)). To clarify the variations of galvanostatic curves and superior cycling performance, the mechanism and morphology changes are systematically investigated. This facile synthesis method is expected to shed light on the preparation of ultrathin 2D materials, whose unique morphologies could easily enable their application in rechargeable batteries.
机译:钠离子电池现在吸引了极大的关注,主要是因为钠资源的丰富和廉价原料。 2D材料具有钠储存的独特结构。其中,过渡金属硫属元素化物由于其可调谐组合物,可显着的结构稳定性,快速离子运输和鲁棒动力学而表现出可充电电池装置的显着潜力。这里,通过剪切混合方法合成超薄TIS2纳米片,并在0.2Ag(-1)的200次循环后表现出优异的循环性能(386mAhg(-1))。为了澄清镀锌曲线和卓越的循环性能的变化,系统地研究了机制和形态变化。这种容易合成方法预计将阐明在超薄2D材料的制备上,其独特的形态可以很容易地使其在可充电电池中的应用。

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  • 来源
    《Advanced energy materials》 |2019年第8期|1803210.1-1803210.8|共8页
  • 作者单位

    Zhengzhou Univ Light Ind Henan Prov Key Lab Surface & Interface Sci Zhengzhou 450001 Henan Peoples R China|Zhengzhou Univ Light Ind Coll Mat & Chem Engn Zhengzhou 450001 Henan Peoples R China|Univ Wollongong Inst Superconducting & Elect Mat Wollongong NSW 2522 Australia;

    Univ Wollongong Inst Superconducting & Elect Mat Wollongong NSW 2522 Australia;

    Univ Wollongong Inst Superconducting & Elect Mat Wollongong NSW 2522 Australia|Wenzhou Univ Coll Chem & Mat Engn Wenzhou 325027 Zhejiang Peoples R China;

    Zhengzhou Univ Light Ind Henan Prov Key Lab Surface & Interface Sci Zhengzhou 450001 Henan Peoples R China|Zhengzhou Univ Light Ind Coll Mat & Chem Engn Zhengzhou 450001 Henan Peoples R China;

    Wenzhou Univ Coll Chem & Mat Engn Wenzhou 325027 Zhejiang Peoples R China;

    Wenzhou Univ Coll Chem & Mat Engn Wenzhou 325027 Zhejiang Peoples R China;

    Univ Wollongong Inst Superconducting & Elect Mat Wollongong NSW 2522 Australia;

    Univ Wollongong Inst Superconducting & Elect Mat Wollongong NSW 2522 Australia;

    Nankai Univ Collaborat Innovat Ctr Chem Sci & Engn Coll Chem Key Lab Adv Energy Mat Chem Minist Educ Tianjin 300071 Peoples R China;

    Univ South China Sch Comp Sci & Technol Hengyang 421001 Peoples R China;

    Nankai Univ Collaborat Innovat Ctr Chem Sci & Engn Coll Chem Key Lab Adv Energy Mat Chem Minist Educ Tianjin 300071 Peoples R China;

    Univ Wollongong Inst Superconducting & Elect Mat Wollongong NSW 2522 Australia;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    exfoliation; few-atomic layers; nanosheets; sodium ion batteries; TiS2;

    机译:去角质;几个原子层;纳米液;钠离子电池;TIS2;

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