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Garnet Solid Electrolyte for Advanced All-Solid-State Li Batteries

机译:用于先进全固态LI电池的石榴石固体电解质

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摘要

High-capacity cathodes and anodes in energy storage area are required for delivering high energy density due to the ever-increasing demands in the applications of electric vehicles and power grids, which suffer from significant safety concerns and poor cycling stability at the current stage. All-solid-state lithium batteries (ASSLBs) have been considered to be particularly promising within the new generation of energy storage, owing to the superiority of safety, wide potential window, and long cycling life. As the key component in ASSLBs, individual solid electrolytes that can meet practical application standards are very rare due to poor performance. To the present day, numerous research efforts have been expended to find applicable solid-state electrolytes and tremendous progress has been achieved, especially for garnet-type solid electrolytes. Nevertheless, the garnet-type solid electrolyte is still facing some crucial dilemmas. Hence, the issues of garnet electrolytes' ionic conductivity, the interfaces between electrodes and garnet solid electrolytes, and application of theoretical calculation on garnet electrolytes are focuses in this review. Furthermore, prospective developments and alternative approaches to the issues are presented, with an aim to improve understanding of garnet electrolytes and promote their practical applications in solid-state batteries.
机译:由于电动车辆和电网应用的应用不断增加的需求,能量存储区域中的高容量阴极和阳极是在电动车辆和电网的应用中产生的高能量密度所需的。由于安全,潜力宽的窗户和长循环寿命长,全固态锂电池(Asslbs)被认为是在新一代的能量存储中尤其有前途。作为ASSLBS中的关键组分,由于性能差,可以满足实际应用标准的单独固体电解质非常罕见。到目前为止,已经消耗了许多研究努力,以查找适用的固态电解质和巨大进展,特别是对于石榴石型固体电解质。然而,石榴石型固体电解质仍面临着一些关键的困境。因此,石榴石电解质离子电导率的问题,电极与石榴石固体电解质之间的界面,以及石榴石电解质的理论计算的应用是侧重于本综述。此外,提出了前瞻性发展和替代方法,旨在提高石榴石电解质的理解,并促进其在固态电池中的实际应用。

著录项

  • 来源
    《Advanced energy materials》 |2021年第2期|2000648.1-2000648.24|共24页
  • 作者单位

    Cent South Univ Coll Chem & Chem Engn Changsha 410083 Peoples R China;

    Cent South Univ Coll Chem & Chem Engn Changsha 410083 Peoples R China;

    Cent South Univ Coll Chem & Chem Engn Changsha 410083 Peoples R China;

    Cent South Univ Coll Chem & Chem Engn Changsha 410083 Peoples R China;

    Cent South Univ Coll Chem & Chem Engn Changsha 410083 Peoples R China;

    Jiangxi Univ Sci & Technol Sch Met & Chem Engn Ganzhou 341000 Peoples R China;

    Jiangxi Univ Sci & Technol Sch Met & Chem Engn Ganzhou 341000 Peoples R China;

    Cent South Univ Coll Chem & Chem Engn Changsha 410083 Peoples R China;

    Cent South Univ Coll Chem & Chem Engn Changsha 410083 Peoples R China;

    Cent South Univ Coll Chem & Chem Engn Changsha 410083 Peoples R China;

    Cent South Univ Coll Chem & Chem Engn Changsha 410083 Peoples R China|Zhengzhou Univ Coll Mat Sci & Engn Zhengzhou 450001 Peoples R China;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    garnet solid electrolytes; ionic conductivity; Li7La3Zr2O12; solid-state batteries;

    机译:石榴石固体电解质;离子电导率;Li7la3zR2O12;固态电池;

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