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Perovskite Solar Cells with Front Surface Gradient

机译:钙钛矿太阳能电池,前表面梯度

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摘要

The recombination flux in a solar cell is determined by not only recombination centers, but also the spatial distribution of minority carriers. For halide perovskite solar cells (PSCs), although there has been a tremendous amount of work focusing on defect passivation, the issue of carrier distribution is not as well studied as for other types of solar cells. Here in this work, with the incorporation of perovskite quantum dots, the concept of the front surface gradient in PSCs using a solution process is successfully realized. Evidenced by multiple characterization techniques, the minority carriers are pushed away from the defect-rich surface by the gradient of valence band maximum, which effectively reduces surface recombination without compromising photocurrent. As a result, the normal structured hybrid PSCs and MAPbI(3) cells exhibit open-circuit voltages exceeding 93% and 90% of their respective Shockley-Queisser limits, and the power conversion efficiencies reach 22.36% and 20.53%, respectively.
机译:太阳能电池中的重组通量不仅由重组中心确定,而且确定少数载体的空间分布。对于卤化物钙钛矿太阳能电池(PSC),虽然已经具有巨大的作品,其专注于缺陷钝化,载体分布问题并不像其他类型的太阳能电池都研究。在这项工作中,通过掺入Perovskite量子点,使用解决方案过程的PSCS中的前表面梯度的概念成功实现。通过多种特征技术证明,少数型载体通过价带最大值的梯度从富缺陷的表面推开,这有效地减少了表面重组而不损害光电流。结果,正常结构化杂交PSC和MAPBI(3)单元表现出超过93%和90%的相应冲击队员限制的开路电压,并且功率转换效率分别达到22.36%和20.53%。

著录项

  • 来源
    《Advanced energy materials》 |2021年第28期|2101080.1-2101080.9|共9页
  • 作者单位

    Soochow Univ Coll Chem Chem Engn & Mat Sci Suzhou 215123 Jiangsu Peoples R China;

    Soochow Univ Coll Chem Chem Engn & Mat Sci Suzhou 215123 Jiangsu Peoples R China;

    Soochow Univ Coll Chem Chem Engn & Mat Sci Suzhou 215123 Jiangsu Peoples R China;

    Soochow Univ Coll Chem Chem Engn & Mat Sci Suzhou 215123 Jiangsu Peoples R China;

    Soochow Univ Coll Chem Chem Engn & Mat Sci Suzhou 215123 Jiangsu Peoples R China;

    Soochow Univ Sch Opt Sci & Engn Suzhou 215006 Jiangsu Peoples R China;

    Soochow Univ Sch Opt Sci & Engn Suzhou 215006 Jiangsu Peoples R China;

    Soochow Univ Sch Opt Sci & Engn Suzhou 215006 Jiangsu Peoples R China;

    Soochow Univ Coll Chem Chem Engn & Mat Sci Suzhou 215123 Jiangsu Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    open-circuit voltage; perovskite solar cells; quantum dots; recombination; surface gradient;

    机译:开路电压;Perovskite太阳能电池;量子点;重组;表面梯度;

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