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Recent Progress of the Solid-State Electrolytes for High-Energy Metal-Based Batteries

机译:高能金属基电池用固态电解质的最新进展

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Secondary batteries based on metal anodes (e.g., Li, Na, Mg, Zn, and Al) are among the most sought-after candidates for next-generation mobile and stationary storage systems because they are able to store a larger amount of energy per unit mass or volume. However, unstable electrodeposition and uncontrolled interfacial reactions occuring in liquid electrolytes cause unsatisfying cell performance and potential safety concerns for the commercial application of these metal anodes. Solid-state electrolytes (SSEs) having a higher modulus are considered capable of inhibiting difficulties associated with the anodes and may enable building of safe all-solid-state metal batteries, yet several challenges, such as insufficient room-temperature ionic conductivity and poor interfacial stability between the electrode and the electrolyte, hinder the large-scale development of such batteries. Here, research and development of SSEs including inorganic ceramics, organic solid polymers, and organic-inorganic hybrid/composite materials for metal-based batteries are reviewed. The comparison of different types of electrolytes is discussed in detail, in the context of electrochemical energy storage applications. Then, the focus of this study is on recent advances in a range of attractive and innovative battery chemistries and technologies that are enabled by SSEs. Finally, the challenges and future perspectives are outlined to foresee the development of SSEs.
机译:基于金属阳极(例如,Li,Na,Mg,Zn和Al)的二次电池是下一代移动和固定存储系统中最抢手的候选电池,因为它们能够每单位存储更多的能量质量或体积。然而,在液体电解质中发生的不稳定的电沉积和不受控制的界面反应导致了不令人满意的电池性能以及对于这些金属阳极的商业应用的潜在的安全隐患。具有较高模量的固态电解质(SSE)被认为能够抑制与阳极相关的困难,并且可以构建安全的全固态金属电池,但还面临一些挑战,例如室温离子电导率不足和界面差电极与电解质之间的稳定性阻碍了这种电池的大规模开发。在此,对用于金属基电池的SSE的研究与开发进行了综述,包括无机陶瓷,有机固体聚合物以及有机-无机混合/复合材料。在电化学能量存储应用的背景下,详细讨论了不同类型电解质的比较。然后,本研究的重点是由SSE支持的一系列有吸引力的创新电池化学和技术的最新进展。最后,概述了挑战和未来前景,以预见上交所的发展。

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