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Aquointermediate Assisted Highly Orientated Perovskite Thin Films toward Thermally Stable and Efficient Solar Cells

机译:Aquaintermediate辅助的高取向钙钛矿薄膜对热稳定和高效的太阳能电池

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摘要

The stability of single-crystalline/monocrystalline-like perovskite film is expected to be better than its microcrystalline counterparts. In the present work, highly orientated perovskite thin films (CH3NH3PbI3-xClx) are prepared by means of aquointermediates assisted solution process. It displays super-duper preferred-orientation along < 110 > direction that is close to the single crystal, and its diffraction intensity ratio of (110)/(310) is nearly two orders of magnitude higher in contrast to the films that prepared by traditional way. Owing to its superior performances, e.g., highly crystallized quality, stress-free inside films, longer electron lifetime, faster temporal response time, etc., the highly orientated perovskite-based solar cells accordingly allow realizing high efficiency while improving its thermal stability.
机译:预计单晶/类单晶钙钛矿薄膜的稳定性要优于其微晶对应物。在本工作中,通过水族中间体辅助溶液法制备了高取向钙钛矿薄膜(CH3NH3PbI3-xClx)。它沿<110>方向显示出接近于单晶的超二聚体择优取向,与传统方法制备的薄膜相比,其衍射强度比(110)/(310)高出近两个数量级。道路。由于其优异的性能,例如高度结晶的质量,无应力的内膜,更长的电子寿命,更快的时间响应时间等,因此高度取向的钙钛矿基太阳能电池可以在提高其热稳定性的同时实现高效率。

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  • 来源
    《Advanced energy materials》 |2017年第2期|1601433.1-1601433.9|共9页
  • 作者单位

    Jinan Univ, Inst New Energy Technol, Coll Informat & Technol, Guangzhou 510632, Guangdong, Peoples R China;

    Jinan Univ, Inst New Energy Technol, Coll Informat & Technol, Guangzhou 510632, Guangdong, Peoples R China;

    Jinan Univ, Inst New Energy Technol, Coll Informat & Technol, Guangzhou 510632, Guangdong, Peoples R China;

    Tsinghua Univ, Key Lab Organ Optoelect & Mol Engn, Minist Educ, Dept Chem, Beijing 100084, Peoples R China;

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  • 正文语种 eng
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  • 关键词

    high orientation and crystallization; perovskite solar cells; thermal stability; thin films;

    机译:高取向和结晶;钙钛矿太阳能电池;热稳定性;薄膜;

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