The Significance of Elemental Sulfur Dissolution in Liquid Electrolyte Lithium Sulfur Batteries

Harks Peter Paul R. M. L.; Robledo Carla B.; Verhallen Tomas W.; Notten Peter H. L.; Mulder Fokko M.

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The Significance of Elemental Sulfur Dissolution in Liquid Electrolyte Lithium Sulfur Batteries

机译：液态电解质锂硫电池中元素硫的溶解意义

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It is shown that the dissolution of elemental sulfur into, and its diffusion through, the electrolyte allows cycling of lithium-sulfur batteries in which the sulfur is initially far removed and electrically insulated from the current collector. These findings help to understand why liquid electrolyte lithium-sulfur batteries can be efficiently cycled, despite the extremely insulating properties of sulfur.

机译：结果表明，元素硫在电解质中的溶解及其在电解质中的扩散可以使锂硫电池循环使用，在锂硫电池中，硫最初被去除得很远，并且与集电器电绝缘。这些发现有助于理解为何尽管硫具有极高的绝缘性能，但液体电解质锂-硫电池仍可以有效地循环使用。

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来源
《Advanced energy materials》 |2017年第3期|1601635.1.1601635.5|共1页
作者
Harks Peter Paul R. M. L.; Robledo Carla B.; Verhallen Tomas W.; Notten Peter H. L.; Mulder Fokko M.;
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作者单位

Delft Univ Technol, MECS, Fac Sci Appl, POB 5045, NL-2600 GA Delft, Netherlands;

Delft Univ Technol, MECS, Fac Sci Appl, POB 5045, NL-2600 GA Delft, Netherlands;

Delft Univ Technol, Dept Radiat Sci & Technol, Mekelweg 15, NL-2629 JB Delft, Netherlands;

Eindhoven Univ Technol, EMD, Dept Chem Engn & Chem, Den Dolech 2, NL-5600 MB Eindhoven, Netherlands|Forschungszentrum Julich, Fundamental Electrochem IEK9, D-52425 Julich, Germany;

Delft Univ Technol, MECS, Fac Sci Appl, POB 5045, NL-2600 GA Delft, Netherlands;

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正文语种 eng
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关键词
batteries; cathodes; lithium; solubility; sulfur;

机译：电池;阴极;锂;溶解度;硫;

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专利

1. Improved Cyclability of Liquid Electrolyte Lithium/Sulfur Batteries by Optimizing Electrolyte/Sulfur Ratio [J] . Sheng S. Zhang Energies . 2012,第12期

机译：通过优化电解质/硫比，改善液体电解质锂/硫电池的循环能力
2. Improved Cyclability of Liquid Electrolyte Lithium/Sulfur Batteries by Optimizing Electrolyte/Sulfur Ratio [J] . Sheng S. Zhang Energies . 2012,第12期

机译：通过优化电解质/硫比，改善液体电解质锂/硫电池的循环能力
3. Perfluoroaryl-Elemental Sulfur SNAr Chemistry in Covalent Triazine Frameworks with High Sulfur Contents for Lithium-Sulfur Batteries [J] . Je Sang Hyun, Kim Hyeon Jin, Kim Jiheon, Advanced Functional Materials . 2017,第47期

机译：锂硫电池中高硫含量的共价三嗪骨架中的全氟芳基元素硫SNAr化学
4. High Transference Number of Li Ion in Highly Concentrated Lithium Bis(trifluoromethanesulfonyl)Amide/Dinitrile Liquid Electrolytes for Lithium Sulfur Batteries [C] . Yosuke Ugata, Kazuhide Ueno, Masayoshi Watanabe, Pacific Rim Meeting on Electrochemical and Solid-State Science . 2020

机译：高浓锂双（三氟甲磺酰基）锂离子锂/二腈液体电解液中锂离子的高转移数
5. From Liquid to Solid: Advanced Composite Separator/Electrolyte Structural Designs for High-Performance Lithium-Sulfur Batteries [D] . Zhu, Pei 2018

机译：从液体到固体：高性能锂硫电池的高级复合隔板/电解质结构设计
6. Lithium–Sulfur Batteries: Hierarchical Micro‐Nanoclusters of Bimetallic Layered Hydroxide Polyhedrons as Advanced Sulfur Reservoir for High‐Performance Lithium–Sulfur Batteries (Adv. Sci. 7/2021) [O] . Weilong Qiu, Gaoran Li, Dan Luo, 2021

机译：锂 - 硫磺电池：双金属分层氢氧化物多面体的等级微纳米烛台作为高性能锂硫电池的先进硫磺水库（ADV。SCI。7/2021）
7. Improved Cyclability of Liquid Electrolyte Lithium/Sulfur Batteries by Optimizing Electrolyte/Sulfur Ratio [O] . Sheng S. Zhang 2012

机译：通过优化电解质/硫比提高液体电解质锂/硫电池的循环性能

The Significance of Elemental Sulfur Dissolution in Liquid Electrolyte Lithium Sulfur Batteries

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