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Designing Efficient Non-Fullerene Acceptors by Tailoring Extended Fused-Rings with Electron-Deficient Groups

机译:通过定制带有电子缺陷基团的延伸熔融环设计高效的非富勒烯受体

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摘要

In the past two years, non-fullerene acceptors including polymers and small molecules have become the focus of many research efforts. Fullerene-free organic solar cells (OSCs) have shown efficiencies of up to 6.8% for solution-processed devices, and even up to 8.4% for vacuum-deposited devices, which have been significantly improved relative to those disclosed 2 years ago (generally <4%). Non-fullerene acceptor materials are a new focus in the OSC field. Tailoring extended fused-rings with electron-deficient groups is an effective strategy for design of acceptors. Here, very recent developments in several systems of fused ring-based electron acceptors, such as halogenated (sub or subna)phthalocyanine, imide-functionalized rylene, and linear fused-rings end capped with electron deficient blocks, are reviewed.
机译:在过去的两年中,包括聚合物和小分子在内的非富勒烯受体已成为许多研究工作的重点。不含富勒烯的有机太阳能电池(OSC)对于溶液处理的设备显示出高达6.8%的效率,对于真空沉积的设备显示出甚至高达8.4%的效率,相对于2年前披露的效率有了显着提高(通常< 4%)。非富勒烯受体材料是OSC领域的新焦点。调整带有电子缺陷基团的延伸稠环是设计受体的有效策略。在这里,回顾了几种基于稠环的电子受体体系的最新进展,例如卤化的(亚或亚萘基)酞菁,酰亚胺官能化的对苯二甲酰亚胺和末端被缺电子的嵌段封端的线性稠环。

著录项

  • 来源
    《Advanced energy materials》 |2015年第20期|1-9|共9页
  • 作者

    Yuze Lin; Xiaowei Zhan;

  • 作者单位

    Department of Chemistry Capital Normal University Beijing P. R. China;

    Department of Materials Science and Engineering College of Engineering Key Laboratory of Polymer Chemistry and Physics of Ministry of Education Peking University Beijing P. R. China;

    Department of Materials Science and Engineering College of Engineering Key Laboratory of Polymer Chemistry and Physics of Ministry of Education Peking University Beijing P. R. China;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    fused rings; n-type semiconductors; non-fullerene acceptors; organic solar cells;

    机译:稠环;n型半导体;非富勒烯受体;有机太阳能电池;

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