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Simultaneously Grasping and Self-Organizing Photoactive Polymers for Highly Reproducible Organic Solar Cells with Improved Efficiency

机译:同时掌握和自组织的光敏聚合物,可提高效率的高可再生有机太阳能电池

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摘要

Polymer-based photovoltaic solar cells have been fabricated with high efficiencies of up to 8% by using a photoactive layer with a bulk heterojunction system, which consists of a blend of a low bandgap donor-acceptor (D-π-A)-type conjugated polymer and a fullerene derivative. There are several strategies for modifying the morphology of the photoactive layer so as to create bi-continuous interpenetrating networks in bulk heterojunction systems: slow growth, solvent annealing, thermal annealing, and the selection of the solvent. For poly(3-hexylthiophene) (P3HT), the thermal annealing method can lead to a remarkably high power conversion efficiency (PCE) compared with that of its pristine film, because P3HT consists of an ordered crystalline phase. On the other hand, D-π-A-type copolymers do not usually exhibit higher crystallinity than P3HT even after annealing.
机译:通过使用具有本体异质结系统的光敏层,聚合物基光伏太阳能电池的效率高达8%,该层由低带隙供体-受体(D-π-A)型共轭共混物组成聚合物和富勒烯衍生物。有几种策略可以改变光敏层的形态,从而在本体异质结系统中创建双连续互穿网络:缓慢生长,溶剂退火,热退火和溶剂选择。对于聚(3-己基噻吩)(P3HT),由于P3HT由有序的结晶相组成,因此与原始膜相比,热退火方法可以显着提高功率转换效率(PCE)。另一方面,即使在退火之后,D-π-A型共聚物通常也没有表现出比P3HT更高的结晶度。

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  • 来源
    《Advanced energy materials》 |2013年第8期|1018-1024|共7页
  • 作者单位

    Department of Chemical Engineering Pohang University of Science and Technology (POSTECH) Pohang, Gyeongbuk, 790-784, Republic of Korea;

    Department of Chemical Engineering Pohang University of Science and Technology (POSTECH) Pohang, Gyeongbuk, 790-784, Republic of Korea;

    Department of Chemical Engineering Pohang University of Science and Technology (POSTECH) Pohang, Gyeongbuk, 790-784, Republic of Korea;

    School of Environmental Science and Engineering Pohang University of Science and Technology (POSTECH) Pohang, Gyeongbuk, 790-784, Republic of Korea;

    Department of Chemical Engineering Pohang University of Science and Technology (POSTECH) Pohang, Gyeongbuk, 790-784, Republic of Korea,School of Environmental Science and Engineering Pohang University of Science and Technology (POSTECH) Pohang, Gyeongbuk, 790-784, Republic of Korea;

    Department of Chemical Engineering Pohang University of Science and Technology (POSTECH) Pohang, Gyeongbuk, 790-784, Republic of Korea;

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