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Solution-Processed (Graphene Oxide)-(d~0 Transition Metal Oxide) Composite Anodic Buffer Layers toward High-Performance and Durable Inverted Polymer Solar Cells

机译:固溶处理的(石墨烯氧化物)-(d〜0过渡金属氧化物)复合阳极缓冲层,用于高性能耐用的倒置聚合物太阳能电池

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摘要

Bulk heterojunction (BHJ) polymer solar cells (PSCs) have been recognized as a promising solution to energy and environmental issues. Recently, significant progress has resulted in power conversion efficiencies (PCEs) of more than 7% in PSCs containing single active layers fabricated by physically blending p-type conjugated polymers and n-type fullerene-derivatives. Even higher PCEs have been reached with improved device architectures and by using interfacial layer modifications. Along with good performance, the practical use of PSCs requires consideration of device stability and fabrication costs. The stability of conventional PSCs using a device architecture of indium tin oxide (ITO)/anodic buffer layer (ABL)/active layer/Ca/Al suffers from rapid oxidation of the low-work-function metal cathodes and the unstable active-layer morphology.
机译:体异质结(BHJ)聚合物太阳能电池(PSC)已被公认为是解决能源和环境问题的有前途的解决方案。近来,重大进展已导致包含通过物理混合p型共轭聚合物和n型富勒烯衍生物制成的单个活性层的PSC的功率转换效率(PCE)超过7%。通过改进的设备架构和使用界面层修改,甚至可以达到更高的PCE。除性能良好外,PSC的实际使用还需要考虑器件的稳定性和制造成本。使用氧化铟锡(ITO)/阳极缓冲层(ABL)/活性层/ Ca / Al的器件结构的常规PSC的稳定性会受到低功函数金属阴极的快速氧化和不稳定的活性层形态的影响。

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  • 来源
    《Advanced energy materials》 |2013年第10期|1279-1285|共7页
  • 作者单位

    Department of Applied Chemistry National Chiao Tung University 1001 Ta Hsueh Rd., Hsinchu, Taiwan 30010;

    Department of Applied Chemistry National Chiao Tung University 1001 Ta Hsueh Rd., Hsinchu, Taiwan 30010;

    Department of Applied Chemistry National Chiao Tung University 1001 Ta Hsueh Rd., Hsinchu, Taiwan 30010;

    Department of Applied Chemistry National Chiao Tung University 1001 Ta Hsueh Rd., Hsinchu, Taiwan 30010;

    Department of Applied Chemistry National Chiao Tung University 1001 Ta Hsueh Rd., Hsinchu, Taiwan 30010;

    Department of Applied Chemistry National Chiao Tung University 1001 Ta Hsueh Rd., Hsinchu, Taiwan 30010;

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