Tailoring Crystal Structure of FA_(0.83)Cs_(0.17)Pbl_3 Perovskite Through Cuanidinium Doping for Enhanced Performance and Tunable Hysteresis of Planar Perovskite Solar Cells

Ngoc Duy Pham; Zhang Chunmei; Tiong Vincent Tiing; Zhang Shengli; Will Geoffrey; Bou Agustin; Bisquert Juan; Shaw Paul E.; Du Aijun; Wilson Gregory J.; Wang Hongxia

首页> 外文期刊>Advanced Functional Materials >Tailoring Crystal Structure of FA_(0.83)Cs_(0.17)Pbl_3 Perovskite Through Cuanidinium Doping for Enhanced Performance and Tunable Hysteresis of Planar Perovskite Solar Cells

【24h】

Tailoring Crystal Structure of FA_(0.83)Cs_(0.17)Pbl_3 Perovskite Through Cuanidinium Doping for Enhanced Performance and Tunable Hysteresis of Planar Perovskite Solar Cells

机译：通过铜掺杂调整FA_（0.83）Cs_（0.17）Pbl_3钙钛矿的晶体结构以提高平面钙钛矿太阳能电池的性能和可调节滞后性

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Current-voltage hysteresis of perovskite solar cells (PSCs) has raised the concern of accurate performance measurement in practice. Although various theories have been proposed to elucidate this phenomenon, the origin of hysteresis is still an open question. Herein, the use of guanidinium cation (Gu(+))-dopant is demonstrated to tailor the crystal structure of mixed-cation formamidinium-cesium lead triiodide (FA(0.83)Cs(0.17)PbI(3)) perovskite, resulting in an improved energy conversion efficiency and tunable current-voltage hysteresis characteristic in planar solar cells. Particularly, when the concentration of Gu-dopant for the perovskite film increases, the normal hysteresis initially observed in the pristine PSC is first suppressed with 2%-Gu-dopant, then changed to inverted hysteresis with a higher Gu-dopant. The hysteresis tunability behavior is attributed to the interplay of charge/ion accumulation and recombination at interfaces in the PSC. Furthermore, compared to the cell without Gu(+)-dopant, the optimal content of 2% Gu(+)-dopant also increases the device efficiency by 14%, reaching over 17% under one sun illumination.

机译：钙钛矿太阳能电池（PSC）的电流-电压磁滞已引起人们对实际性能测量的关注。尽管提出了各种理论来阐明这种现象，但是磁滞的起源仍然是一个悬而未决的问题。在这里，已证明使用胍阳离子（Gu（+））-掺杂剂可以定制混合阳离子甲ami-铯三碘化铅（FA（0.83）Cs（0.17）PbI（3））钙钛矿的晶体结构。改进了平面太阳能电池的能量转换效率和可调的电流-电压磁滞特性。特别地，当钙钛矿膜的Gu-掺杂剂的浓度增加时，最初在原始PSC中观察到的正常磁滞首先被2％-Gu-掺杂剂抑制，然后变为具有更高的Gu-掺杂剂的反向磁滞。磁滞可调谐性行为归因于PSC界面处电荷/离子累积和重组的相互作用。此外，与不添加Gu（+）掺杂剂的电池相比，添加2％Gu（+）掺杂剂的最佳含量还可将器件效率提高14％，在一次阳光照射下可达到17％以上。

著录项

来源
《Advanced Functional Materials》 |2019年第1期|1806479.1-1806479.10|共10页
作者
Ngoc Duy Pham; Zhang Chunmei; Tiong Vincent Tiing; Zhang Shengli; Will Geoffrey; Bou Agustin; Bisquert Juan; Shaw Paul E.; Du Aijun; Wilson Gregory J.; Wang Hongxia;
展开▼
作者单位

Queensland Univ Technol, Sch Chem Phys & Mech Engn, Fac Sci & Engn, Brisbane, Qld 4001, Australia;

Queensland Univ Technol, Sch Chem Phys & Mech Engn, Fac Sci & Engn, Brisbane, Qld 4001, Australia;

Queensland Univ Technol, Sch Chem Phys & Mech Engn, Fac Sci & Engn, Brisbane, Qld 4001, Australia;

Queensland Univ Technol, Sch Chem Phys & Mech Engn, Fac Sci & Engn, Brisbane, Qld 4001, Australia;

Queensland Univ Technol, Sch Chem Phys & Mech Engn, Fac Sci & Engn, Brisbane, Qld 4001, Australia;

Univ Jaume 1, Inst Adv Mat INAM, Castellon de La Plana 12006, Spain;

Univ Jaume 1, Inst Adv Mat INAM, Castellon de La Plana 12006, Spain;

Univ Queensland, Sch Chem & Mol Sci, St Lucia, Qld 4072, Australia;

Queensland Univ Technol, Sch Chem Phys & Mech Engn, Fac Sci & Engn, Brisbane, Qld 4001, Australia;

CSIRO Energy, Mayfield West, NSW 2304, Australia;

Queensland Univ Technol, Sch Chem Phys & Mech Engn, Fac Sci & Engn, Brisbane, Qld 4001, Australia;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词
band energy alignment; efficiency enhancement; guanidinium ion doping; perovskite solar cells; tunable hysteresis;

机译：带能对准;效率增强;胍鎓离子掺杂;钙钛矿太阳能电池;可调谐磁滞;

相似文献

外文文献
中文文献
专利

1. In Situ Measurement of Electric-Field Screening in Hysteresis-Free PTAA/FA_(0.83)Cs_(0.17)Pb(I_(0.83)Br_(0.17))_3/C60 Perovskite Solar Cells Gives an Ion Mobility of ～3 × 10~(-7) cm~2/(V s), 2 Orders of Magnitude Faster than Reported for Metal-Oxide-Contacted Perovskite Cells with Hysteresis [J] . Bertoluzzi Luca, Belisle Rebecca A., Bush Kevin A., Journal of the American Chemical Society . 2018,第40期

机译：无磁滞PTAA / FA_（0.83）Cs_（0.17）Pb（I_（0.83）Br_（0.17））_ 3 / C60钙钛矿太阳能电池的电场屏蔽原位测量给出的离子迁移率为〜3×10〜（ -7）cm〜2 /（V s），比金属氧化物接触的具有滞后作用的钙钛矿电池快2个数量级
2. Highly crystalline Nb-doped TiO2 nanospindles as superior electron transporting materials for high-performance planar structured perovskite solar cells [J] . Lv Yinhua, Cai Bing, Ma Qingshan, RSC Advances . 2018,第37期

机译：高度结晶的NB掺杂TiO2纳米件作为高性能平面结构钙钛矿太阳能电池的高级电子传输材料
3. Highly crystalline Nb-doped TiO2 nanospindles as superior electron transporting materials for high-performance planar structured perovskite solar cells [J] . Yinhua Lv, Bing Cai, Qingshan Ma, RSC Advances . 2018,第37期

机译：高结晶Nb掺杂的TiO2纳米锭是高性能平面结构钙钛矿太阳能电池的优良电子传输材料
4. Hybrid 2D/3D Perovskite Film with Enhanced Crystallinity via PEAI Passivation in Perovskite Solar Cells [C] . Xin Rong, Xin Yao, Zugang Liu International conference on optoelectronics and measurement . 2019

机译：Hybrid 2D / 3D Perovskite薄膜，通过Peai钝化在Perovskite太阳能电池中具有增强的结晶度
5. Controlling the Crystallization of Organo-Lead-Halide Perovskite for High-Performance and Stable Perovskite Solar Cells. [D] . Wang, Baohua. 2016

机译：为高性能和稳定的钙钛矿太阳能电池控制有机铅卤化物钙钛矿的结晶。
6. Enhanced Performance of Planar Perovskite Solar Cells Using Low-Temperature Solution-Processed Al-Doped SnO2 as Electron Transport Layers [O] . Hao Chen, Detao Liu, Yafei Wang, 2017

机译：使用低温溶液处理的Al掺杂SnO2作为电子传输层的平面钙钛矿太阳能电池的增强性能
7. Highly crystalline Nb-doped TiO2 nanospindles as superior electron transporting materials for high-performance planar structured perovskite solar cells [O] . Yinhua Lv, Bing Cai, Qingshan Ma, 2018

机译：高度结晶的NB掺杂TiO2纳米件作为高性能平面结构钙钛矿太阳能电池的高级电子传输材料

Tailoring Crystal Structure of FA_(0.83)Cs_(0.17)Pbl_3 Perovskite Through Cuanidinium Doping for Enhanced Performance and Tunable Hysteresis of Planar Perovskite Solar Cells

摘要

著录项

相似文献

相关主题

期刊订阅