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Bioinspired Color Changing Molecular Sensor toward Early Fire Detection Based on Transformation of Phthalonitrile to Phthalocyanine

机译:基于邻苯二甲腈转化为酞菁的生物启发变色分子传感器,用于早期火灾探测

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摘要

The fire detection plays a critical role in the maintenance of public security. Previous approaches of early fire warning, based on smoke or temperature response must be set in the proximity of a fire. They cannot provide the additional information of fire location or size and are susceptible to complicated situations. It is still a big challenge to make rapid and accurate early fire warning in precombustion because of the lack of reliable alarm signals. Herein, a precursor molecular sensor (PMS) is designed and synthesized that can present the chemical structure transformation to form phthalocyanines (Pcs) and release a color change signal at about 180 degrees C, learning from the plant chlorophyll metabolism. Further, the PMS is assembled to an early fire warning component (EWC) and an intelligent image recognition algorithm is introduced for unburned fire detection. The EWC generates a colorful alarm within 20 s at 275 degrees C. Therefore, the facile PMS provides a reliable real-time monitoring strategy to the early fire warning detection in precombustion.
机译:火灾探测在维护公共安全中起着至关重要的作用。必须在火灾附近设置基于烟雾或温度响应的早期火灾预警方法。它们无法提供火源位置或大小的附加信息,并且易受复杂情况的影响。由于缺乏可靠的报警信号,因此在燃烧前快速准确地进行火灾预警仍然是一个很大的挑战。本文中,设计并合成了前体分子传感器(PMS),该分子可以呈现化学结构转化以形成酞菁(Pcs),并在大约180摄氏度下释放变色信号,这是从植物叶绿素代谢中学习到的。此外,将PMS组装为早期火灾预警组件(EWC),并引入了智能图像识别算法以进行未燃火灾检测。 EWC在275摄氏度下20秒内发出彩色警报。因此,便捷的PMS为预燃中的早期火灾预警检测提供了可靠的实时监控策略。

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  • 来源
    《Advanced Functional Materials》 |2019年第8期|1806586.1-1806586.8|共8页
  • 作者单位

    Sichuan Univ, Coll Chem, State Key Lab Polymer Mat Engn, Natl Engn Lab Ecofriendly Polymer Mat Sichuan, Chengdu 610064, Sichuan, Peoples R China;

    Sichuan Univ, Coll Chem, State Key Lab Polymer Mat Engn, Natl Engn Lab Ecofriendly Polymer Mat Sichuan, Chengdu 610064, Sichuan, Peoples R China;

    Sichuan Univ, Coll Chem, State Key Lab Polymer Mat Engn, Natl Engn Lab Ecofriendly Polymer Mat Sichuan, Chengdu 610064, Sichuan, Peoples R China;

    Sichuan Univ, Coll Chem, State Key Lab Polymer Mat Engn, Natl Engn Lab Ecofriendly Polymer Mat Sichuan, Chengdu 610064, Sichuan, Peoples R China;

    Sichuan Univ, Coll Chem, State Key Lab Polymer Mat Engn, Natl Engn Lab Ecofriendly Polymer Mat Sichuan, Chengdu 610064, Sichuan, Peoples R China;

    Sichuan Univ, Coll Chem, State Key Lab Polymer Mat Engn, Natl Engn Lab Ecofriendly Polymer Mat Sichuan, Chengdu 610064, Sichuan, Peoples R China;

    Sichuan Univ, Coll Chem, State Key Lab Polymer Mat Engn, Natl Engn Lab Ecofriendly Polymer Mat Sichuan, Chengdu 610064, Sichuan, Peoples R China;

    Sichuan Univ, Coll Chem, State Key Lab Polymer Mat Engn, Natl Engn Lab Ecofriendly Polymer Mat Sichuan, Chengdu 610064, Sichuan, Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    color change; early fire detection; image recognition algorithm; molecular sensor; phthalocyanine;

    机译:颜色变化;早期火灾探测;图像识别算法;分子传感器;酞菁;

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