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Highly Stable Ni-Based Flexible Transparent Conducting Panels Fabricated by Laser Digital Patterning

机译:通过激光数字图案制作的高度稳定的镍基柔性透明导电板

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摘要

A novel simple laser digital patterning process to fabricate Ni-based flexible transparent conducting panels using solution-processed nonstoichiometric nickel oxide (NiOx) thin films and their applications for flexible transparent devices are reported in this study. A large-scale synthesis route to produce NiOx nanoparticle (NP) ink is also demonstrated. A low-power continuous-wave laser irradiation photothermochemically reduces and sinters selected areas of a NiOx NP thin film to produce Ni electrode patterns. Owing to the innovative NiOx NP ink and substantially lowered applied laser power density, Ni conductors can be fabricated, for the first time to the best of the authors' knowledge, even on a polyethylene terephthalate substrate, which is known to have one of the lowest glass-transition temperatures among polymers. The resultant Ni electrodes exhibit a high-temperature oxidation resistance up to approximately 400 degrees C, and high corrosion resistance in tap water and even in seawater. Moreover, a superior mechanical stability of the Ni conductors is confirmed by tape-pull, ultrasonic-bath, bending/twisting, and cyclic bending (up to 10 000 cycles) tests. Finally, flexible transparent touch screen panels and electrical heaters are fabricated with mesh-type Ni conductors to demonstrate possible applications.
机译:在这项研究中报道了一种新颖的简单的激光数字图案化工艺,该工艺使用溶液处理的非化学计量的氧化镍(NiOx)薄膜来制造Ni基柔性透明导电面板,并将其应用于柔性透明器件。还展示了生产NiOx纳米粒子(NP)墨水的大规模合成路线。低功率连续波激光辐照光热化学还原并烧结NiOx NP薄膜的选定区域,以产生Ni电极图案。由于采用了创新的NiOx NP墨水,并且大大降低了所施加的激光功率密度,因此,即使在已知的聚对苯二甲酸乙二酯衬底中,镍导体也可以首次制造,但据作者所知,这是第一次。聚合物之间的玻璃化转变温度。所得的Ni电极表现出高达约400℃的高温抗氧化性,并且在自来水中甚至在海水中都具有高耐腐蚀性。此外,通过带拉,超声浴,弯曲/扭曲和循环弯曲(最多10000次循环)测试,证实了Ni导体具有优异的机械稳定性。最后,用网状镍导体制造柔性透明触摸屏面板和电加热器,以展示可能的应用。

著录项

  • 来源
    《Advanced Functional Materials》 |2019年第8期|1806895.1-1806895.10|共10页
  • 作者单位

    Gachon Univ, Laser & Thermal Engn Lab, Dept Mech Engn, 1342 Seongnamdaero, Seongnam 13120, Gyeonggi, South Korea;

    Seoul Natl Univ, Appl Nano & Thermal Sci Lab, Dept Mech Engn, 1 Gwanak Ro, Seoul 08826, South Korea;

    Seoul Natl Univ, Appl Nano & Thermal Sci Lab, Dept Mech Engn, 1 Gwanak Ro, Seoul 08826, South Korea;

    Gachon Univ, Laser & Thermal Engn Lab, Dept Mech Engn, 1342 Seongnamdaero, Seongnam 13120, Gyeonggi, South Korea;

    Seoul Natl Univ, Appl Nano & Thermal Sci Lab, Dept Mech Engn, 1 Gwanak Ro, Seoul 08826, South Korea;

    Seoul Natl Univ, Appl Nano & Thermal Sci Lab, Dept Mech Engn, 1 Gwanak Ro, Seoul 08826, South Korea;

    Kyungpook Natl Univ, Novel Appl Nano Opt Lab, Dept Phys, 80 Daehak Ro, Daegu 41566, South Korea;

    Hanyang Univ, Dept Mech Engn, 55 Hanyangdaehak Ro, Ansan 15588, South Korea;

    Seoul Natl Univ, Appl Nano & Thermal Sci Lab, Dept Mech Engn, 1 Gwanak Ro, Seoul 08826, South Korea|Seoul Natl Univ, Inst Engn Res, Inst Adv Machinery & Design SNU IAMD, 1 Gwanak Ro, Seoul 08826, South Korea;

    Gachon Univ, Laser & Thermal Engn Lab, Dept Mech Engn, 1342 Seongnamdaero, Seongnam 13120, Gyeonggi, South Korea;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    laser digital patterning; Ni electrode; NiOx nanoparticle ink; touch screen panels; transparent flexible heaters;

    机译:激光数字图案;镍电极;纳米氧化镍镍油墨;触摸屏面板;透明柔性加热器;

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