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Semitransparent, Flexible, and Self-Powered Photodetectors Based on Ferroelectricity-Assisted Perovskite Nanowire Arrays

机译:基于铁电辅助钙钛矿纳米线阵列的半透明,柔性和自供电光电探测器

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摘要

Transparent and flexible photodetectors hold great promise in next-generation portable and wearable optoelectronic devices. However, most of the previously reported devices need an external energy power source to drive its operation or require complex fabrication processes. Herein, designed is a semitransparent, flexible, and self-powered photodetector based on the integrated ferroelectric poly(vinylidene-fluoride-trifluoroethylene) (P(VDF-TrFE)) and perovskite nanowire arrays on the flexible polyethylene naphthalate substrate via a facile imprinting method. Through optimizing the treatment conditions, including polarization voltage, polarization time, and the concentration of P(VDF-TrFE), the resulting device exhibits remarkable detectivity (7.3 x 10(12) Jones), fast response time (88/154 mu s) at zero bias, as well as outstanding mechanical stability. The excellent performance is attributed to the efficient charge separation and transport originating from the highly oriented 1D transport pathway and the polarization-induced internal electric field within P(VDF-TrFE)/perovskite hybrid nanowire arrays.
机译:透明而灵活的光电探测器在下一代便携式和可穿戴光电设备中具有广阔的前景。但是,大多数先前报告的设备都需要外部能源来驱动其运行或需要复杂的制造过程。本文设计了一种基于半透明,柔性,自供电的光电探测器,该探测器基于集成的铁电聚偏二氟乙烯-三氟乙烯(P(VDF-TrFE))和钙钛矿纳米线阵列,并通过一种便捷的压印方法在柔性的萘二甲酸乙二醇酯衬底上。通过优化处理条件,包括极化电压,极化时间和P(VDF-TrFE)的浓度,所得器件具有出色的检测能力(7.3 x 10(12)Jones),响应时间短(88/154μs)零偏压以及出色的机械稳定性。优异的性能归因于高效的电荷分离和传输,其源自高度定向的1D传输路径以及P(VDF-TrFE)/钙钛矿杂化纳米线阵列中极化诱导的内部电场。

著录项

  • 来源
    《Advanced Functional Materials》 |2019年第24期|1901280.1-1901280.9|共9页
  • 作者单位

    Soochow Univ, Sch Phys Sci & Technol, Jiangsu Key Lab Thin Films, CECMP, Suzhou 215006, Peoples R China;

    Soochow Univ, Sch Phys Sci & Technol, Jiangsu Key Lab Thin Films, CECMP, Suzhou 215006, Peoples R China;

    Soochow Univ, Sch Phys Sci & Technol, Jiangsu Key Lab Thin Films, CECMP, Suzhou 215006, Peoples R China;

    Soochow Univ, Sch Phys Sci & Technol, Jiangsu Key Lab Thin Films, CECMP, Suzhou 215006, Peoples R China;

    Soochow Univ, Sch Phys Sci & Technol, Jiangsu Key Lab Thin Films, CECMP, Suzhou 215006, Peoples R China;

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  • 正文语种 eng
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  • 关键词

    flexible; perovskite nanowire arrays; photodetector; self-powered; semitransparent;

    机译:柔性;钙钛矿纳米线阵列;光电探测器;自供电;半透明;

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