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Emerging Functional Porous Polymeric and Carbonaceous Materials for Environmental Treatment and Energy Storage

机译:新出现的功能多孔聚合物和用于环境处理和储能的碳质材料

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摘要

The demand for practical and cost-effective environmental treatment and energy storage materials is exploding. Porous polymeric and carbonaceous materials have attracted tremendous interest on account of their well-developed porosity and tunable surface chemistry. Functionalization of pore structures further enhances their properties for environmental treatment and energy storage. Herein, the procedures for functionalization of porous structures are introduced, including predesign and postsynthetic strategies. Subsequently, the important advancements of emerging porous polymers for environmental treatment in sorption (e.g., organic micropollutant adsorption, heavy metal ion removal, radionuclide extraction, and oil absorption) and membrane separation (e.g., aqueous micropollutant separation, organic solvent nanofiltration, desalination and pervaporation), as well as for energy storage ranging from the electrodes and separators of batteries to supercapacitor electrodes are highlighted. Moreover, given the combined merits of high intrinsic conductivity, porosity, and physicochemical stability, novel polymer-based porous carbons for energy storage are also highlighted. Key functionalization chemistry for each application is discussed and an in-depth understanding of the structure-property relationships of these functional porous materials is provided. Finally, the challenges and perspectives of emerging functional porous polymeric and carbonaceous materials for environmental treatment and energy storage are proposed.
机译:对实际和经济高效的环境处理和储能材料的需求正在爆炸。由于其发育良好的孔隙率和可调表面化学,多孔聚合物和碳质材料引起了巨大的兴趣。孔隙结构的官能化进一步增强了它们的环境处理和能量储存的性质。这里,引入了多孔结构的功能化程序,包括预测和后期策略。随后,在吸附中的环境处理中出现的多孔聚合物的重要进步(例如,有机微量循环吸附,重金属离子去除,放射性核素萃取和吸油)和膜分离(例如,微拷贝分离,有机溶剂纳米滤乱,脱盐和鸟类)并且突出了从电池和电池的隔板到超级电容器电极的能量存储。此外,鉴于高固有电导率,孔隙率和物理化学稳定性的组合优点,还突出了新的基于聚合物的多孔碳碳。讨论了每个应用的关键官能化化学,并提供了对这些功能多孔材料的结构性质关系的深入理解。最后,提出了新出现的功能多孔聚合物和用于环境处理和能量储存碳质材料的挑战和观点。

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